邻苯二甲酸酯的摇瓶生物降解规律研究-环境科学学报.pdfVIP

22 3 Vol. 22, No. 3 2002 5 ACTA SC ENT AE C RCUMSTANT AE May, 2002 :2002 : X172 :A 1, 2 1 2 1 夏凤毅 , 郑 平, 周 琪, 冯孝善 ( 1. , 310029; 2. , 200092) : 9 , , , ( k ) , lnk = 00262x 2 - 0667x + 2152 ( r = 0976) ; b b , t 12= 00391x 2 + 00953x - 00259 ( r = 0972) . ( DMP) 60 mgL- 1 , , 500 mgL- 1 , (DEP) . : ; ; ; Shake flask biodegradation of phthalic acid esters 1, 2 1 2 1 X A Fengyi , ZHENG Ping , ZHOU Qi , FENG Xiaoshan ( 1. Department of Environment al Engineering, Zhejiang Uni versity, Hangzhou 310029; 2. State Key Lab. of Pollution Control and Resource Reuse, Tongji University, Shanghai 200092) Abstract: Biodegradation experiments of PAEs were carried out with activated sludge. The results showed that biodegradation rat es of PAEs fit ted the first kinetics equat ion and rate constants decreasedwith the increase of alkyl chain length. There were correlations between alkyl chain length and biodegradation rate constant ( kb ) and halflif e time( t12 ) : relationship equat ion is lnkb = 00262x 2 - 0667x + 2152, r = 0976; t = 00391x 2 + 00953x - 00259, r = 0972. Concentration of DMP and high phthalate concentrat ion affected the biodegradation 12 rates of DMP. Keywords: phthalic acid esters; shake flask; biodegradat ion; relat ionship ( PAEs) . [ 1] 14 , 6 EPA ; 3 [ 2] [ 3 5] .