冷加工与敏化对304L不锈钢应力腐蚀性质之影响.pdf

冷加工與敏化對304L 不銹鋼應力腐蝕性質之影響 防蝕工程　第二十四卷第一期　第61 ~ 70 頁　2010 年3 月 Journal of Chinese Corrosion Engineering, Vol. 24, No. 1, pp. 61 ~ 70 (2010) 304L 1 2 2 1 賴建霖* 、開物 、蔡履文 、陳鈞 Effect of Cold Work and Sensitization Treatment on the Stress Corrosion Cracking of 304L Stainless Steels 1 2 2 1 C. L. Lai* , K. Wu , L.W. Tsay , C. Chen Received 20 July 2009; received in revised form 6 December 2009; accepted 20 February 2010 本研究針對 304L 不銹鋼探討冷加工與敏化熱處理對其顯微組織、機械性質及其於 80 °C 之 40 wt% 氯化鎂溶液中之應力腐蝕特性之影響。實驗結果顯示，冷加工導致加工硬化 伴隨材料缺陷增加，加工應變並促使應變誘發沃斯田鐵至麻田散鐵相變態。氯化鎂環境測 試結果顯示，冷加工後因材料缺陷增加對氫原子之捕集位置，缺口拉伸強度下降量僅 11% ， 較固溶處理試片之 25%明顯降低。冷加工後再經敏化熱處理之試片，因於晶界附近生成應 力誘發麻田散鐵相變態，提供氫原子較快速之擴散途徑，缺口拉伸強度下降量增加至27% ， 且破斷型貌由冷加工試片之準劈裂轉變成沿晶破裂。 關鍵詞：不銹鋼；應力腐蝕；氫脆。 ABSTRACT The effect of cold work and sensitization treatment on the microstructure, mechanical property and stress corrosion cracking of 304L stainless steels in an 80 °C 40 wt% MgCl2 solution was investigated in this research. The results showed that cold work caused obvious work- hardening in the 304L stainless steel plate along with a great increase in defects, and it also enhanced strain-induced martensite in the steel. Increased trapping sites for hydrogen due to the defects resulted in a much lower NTS loss of the cold-rolled specimen