聚合物辐照后氧化性能研究.pptxVIP

聚合物辐照后氧化性能研究;文献1、γ射线辐照，光引发，热引发对PP结构的影响;Fig. 4. Subtraction of the initial spectrum from the spectra recorded after irradiation at 48 kGy under oxygen for PPi (i), PPs (s) and PPa (a) films in the 3800–3000 cm-1 (A) and in the 1900–1500 cm-1 (B) region.;分析氧化产物;SF4可与脂肪族羧酸反应，并在1835-1845cm-1出现特征峰。经SF4处理后，PP薄膜在1838处出现吸收峰，表明辐照后有羧酸生成。;Table I. FTIR Values for Identification and Quantification of Polyolefin Oxidation Products;;NO处理;不同方法引发的iPP氧化产物;Figure 7. Kinetic accumulation of iPP thermally initiated oxidation products. Note that the time axis does not begin at zero.;PP氧化的机理;酮、醇的生成;结论：PE的主要氧化产物是酮，还