非平衡复合氯化物工质对吸附解吸动力模型分析.docxVIP

中国工程热物理学会 传热传质学会会议论文 学术会议论文 编号：153012 非平衡复合氯化物工质对吸附/解吸动力模型分析 周志松，王丽伟，江龙，高鹏，王如竹 （上海交通大学制冷与低温工程研究所，动力机械与工程教育部重点实验室，上海市闵行区东川路800号，上海200240） 摘要：为了更加贴近于生产实验，非平衡条件下金属氯化物吸附解吸特性就显得非常必要，实验结果表明，在相同的冷凝/蒸发条件下，金属氯化物吸附（解吸）氨的摩尔数随着温度的变化而变化，说明了非平衡吸附/解吸过程为双变量控制，而不是单变量控制的结果。这与理论的Claperon曲线有较大的差别。为了验证研究结果，研究人员对吸附剂的等压吸附过程进行了测试。结果发现吸附过程与平衡压力/温度曲线相符合，而解吸存在着严重的滞后现象。为了探索解吸滞后与吸附热之间的关系，首先建立了吸附率的吸附解吸动力模型，其中吸附过程符合物理吸附中的D-A方程，化学吸附则包含了物理吸附中的D-A方程以及spinner建立的化学吸附模型。 关键词：非平衡吸附解吸，MnCl2-NH3，NH4Cl- NH3，吸附动力模型 Non-equilibrium adsorption/desorption kinetic processes for composite adsorbents of chlorides - ammonia working pairs Z.S. Zhou, L.W. Wang*, L. Jiang, P. Gao, R.Z. Wang （Institute of Refrigeration and Cryogenics, Key Laboratory of Power Machinery and Engineering of Ministry of Education, Shanghai Jiao Tong University, Shanghai, 200240, China） Abstract: The adsorption/desorption characteristics under the non-equilibrium conditions are extremely important for the refrigeration because they are more related with the actual working processes. The experimental test unit is set up, and the p-T-x curves of different working pairs are tested under the non-equilibrium working conditions. The results show that non-equilibrium adsorption/desorption processes are related with dual variables rather than a single variable, which is vital for the equilibrium condition. In order to analyze the experimental results in detail, we tested the isobaric adsorption/desorption processes of adsorption bed, and the hysteresis phenomena of different working pairs are analyzed. Adsorption/desorption dynamic models are studied. The research shows that for adsorption process the model is in accord with D-A equation, but for the desorption process both D-A equation and spinner model should be considered. Keywords: non-equilibrium condition, adsorption working pair, kinetic model 0前言 随着当今社会的发展、能源消耗以及人们对生活质量要求的提高，能源危机和环境污染问题受到了全世界的关注，而在现实生活