高碘酸钠对棉纤维选择性氧化工艺和性能研究.PDFVIP

安徽农业大学学报, 2011, 38(5): 812-816 Journal of Anhui Agricultural University [DOI]CNKI：34-1162/S1433.029 网络出版时间：2011-08-29 14:33:21 [URL]/kcms/detail/34.1162.S1433.029.html 高碘酸钠对棉纤维的选择性氧化工艺及性能研究 1 2 1 1 王 浩 ，陈宇岳 ，黄 晨 ，刘 娜 (1. 安徽农业大学轻纺工程与艺术学院，合肥 230036 ；2. 苏州大学纺织与服装工程学院，苏州 215021) 摘 要：采用高碘酸盐对棉纤维进行仲羟基选择性氧化，制备了二醛基纤维素。通过正交设计直观分析法对制 备工艺进行优化。结果表明，以棉纤维的强力和醛基含量为综合指标，制备的较优工艺条件是高碘酸钠氧化剂浓度 为 2 g·L-1 、氧化温度为40 ℃，氧化时间为2 h 。通过FT-IR 和 X 射线衍射测试可知经高碘酸盐处理后，棉纤维素大 分子链中含有新生成的活性基团醛基，但其结晶度有所降低。与原棉纤维相比，经较优工艺氧化的棉纤维弹性变形 和吸水性能有所提高，初始模量稍有下降从而纤维略变柔软。 关键词：选择性氧化；高碘酸盐；棉纤维；工艺；性能 中图分类号：TS102.211 文献标识码：A 文章编号：1672−352X (2011)05−0812−05 Study on the process and properties of selective oxidized cotton fiber by sodium periodate 1 2 1 1 WANG Hao , CHEN Yu-yue , HUANG Chen , LIU Na (1. School of Light-Textile Engineering and Art, Anhui Agricultural University, Hefei 230036; 2. College of Textile and Clothing Engineering, Soochow University, Soochow 215021) Abstract: In this paper, dialdehyde cellulose was prepared by periodate selective oxidation of secondary hy- droxyl groups of cotton fiber. The preparation process was optimized by orthogonal design-direct analysis. The results showed that the optimum preparation process was determined as sodium periodate 2 g·L-1, oxidized at 40℃ for 2 h ,taken dialdehyde content and strength loss rate as indices. It can be obtained that after periodate treatment, new activated aldehyde groups were generated on cotton cellulose molecular chain while the crystallinity of cot- ton fiber was decreased by FI-IR and XRD(x-ray diffraction) analysis. Compared with native cotton, elastic de- form and water absorption