《木质素改性球形酚醛树脂的制备论文》-毕业设计（论文）.docVIP

福州大学本科生毕业设计(论文) PAGE 30 PAGE 29 木质素改性球形酚醛树脂的制备 摘 要 多孔球形酚醛树脂在吸附中有广泛应用，而木质素作为工业生产中的废弃物可以用来合成酚醛树脂。本文以苯酚和甲醛为反应单体，采用聚乙烯醇（PVA1788）作分散剂，三乙胺（TEA）作碱催化剂，六次甲基四胺（HMTA）作交联剂，利用水相悬浮缩聚法制备了球形酚醛树脂。在稳定悬浮缩聚体系引入致孔剂，制备多孔的酚醛树脂微球,并对木质素部分替代苯酚制备多孔酚醛树脂微球进行初步探讨。 通过实验确定了水相悬浮缩聚法制备酚醛树脂珠体基本合成工艺：先将苯酚、甲醛、三乙胺加入到一定浓度的PVA水溶液，在95～97℃反应40 min后，加入HMTA，继续反应4h，再用1mol/L的盐酸溶液调节PH值至2，固化反应1h，可得到形态规整的珠体；并发现PVA浓度对酚醛树脂珠体粒度影响很大，粒度分布较宽。 甲苯致孔得到多孔球形酚醛树脂微球，粒径分布较无致孔剂时窄,孔径在2μ以上；甲苯用量5克，PVA浓度为0.375%时，得到的粒径在20～80目间的粒子数量达90%；提高甲苯量能增大多孔球形酚醛树脂微球比表面积，但加宽粒径分布；且高甲苯添加量时，PVA浓度对缩聚产物形态影响非常显著，低PVA浓度下易结块，高PVA浓度下得细粉（粒径小于200目）。邻苯二甲酸二丁酯（DOP）致孔得到外表面光滑内表面多孔的酚醛树脂中空微球，粒径分布也窄，粒径在20目～80目间粒子数量占80%以上。木质素替代苯酚制备多孔球形酚醛树脂，木质素能参与反应成球，但球形度稍差，孔径也更小。 关键词：悬浮缩聚，木质素，酚醛树脂微球，致孔剂 Preparation of the Phenolic Microspheres and Modification by Lignin Abstract Porous phenolic sphere is widely used as absorption resin and lignin from industrial waste can be used to synthesize phenolic resin. The aqueous suspension condensation polymerization to prepare spherical phenolic beads was studied using poly(vinyl alcohol) (PVA) , triethylamine (TEA), and hexamethylenetetramine (HMTA) as stabilizer, basic catalyst, and basic crosslinking agent respectively. Porogenic agents were introduced to the stable suspension condensation system to prepare porous phenolic resin microspheres, and using lignin as part of phenol alternative to prepare porous phenolic microspheres is primarily studied. The basic process for the phenolic beads prepared by the aqueous suspension condensation are established through experiment. Phenol, formaldehyde, triethylamine are firstly added to PVA solution at a certain concentrion and react at 95 ~ 97 ℃ for 40 min,then HMTA is added and reacted for another 4 h, and finally 1M hydrochloric acid is droplet add to condition pH value of reaction systems to 2 and cure for 1 h more, the obtained beads is regular in form and found PVA concentration play a important role on the size of phenolic beads and particle size distribution The phenolic microsphere