煤泥絮团分散剂的应用研究.docxVIP

煤泥絮团分散剂的应用研究 戚冬伟以，宋玲玲2,冯莉\蒋欧2 ((1.宿州职业技术学院基础教学部，安徽宿州234101; 2.中国矿业大学化工学院，江苏 徐州 221116) 摘 要：分别采用六偏磷酸钠、竣甲基纤维素钠(CMC)作为分散剂，对夹河煤、开滦煤进行分散实验， 以自制水煤浆体系黏度大小为表征方法，验证其分散效果；并经由浮选实验结果验证分散处理之后的煤泥 浮选效果。结果表明：两种分散剂均使各分散体系的黏度值有所增加，达到了分散煤泥絮团的目的。经六 偏磷酸钠分散后，夹河煤和开滦煤的精煤灰分及回收率，在一定范围内均有所提高，但是规律性不强；CMC 分散性很好，但因其与捕收剂之间具有排斥作用，难以浮选出精煤，不可用于煤泥浮选浆体分散。 关键词：煤泥絮团；分散剂；六偏磷酸钠；竣甲基纤维素钠 中图分类号：X703 文献标识码：A Study for application of slime-flocculate dispersants Qi Dongwei1,2, Song Lingling2, Feng Li2, Jiang Ou2 ((1.Basic Courses Teaching Department of Suzhou Vocational Technical College, Suzhou, Anhui 234101, China ； 2.School of Chemical Engineering and Technology, China University of Mining and Technology, Xuzhou, Jiangsu 221116) Abstract: Conducted dispersion experiments for Jiahe and Kailuan coal respectively, using sodium hexametaphosphate, sodium carboxymethyl cellulose (CMC) as dispersants. The dispersion effect was verified by viscosity of CWS, and the result of coal flotation after decentralization verified by the flotation experiment. The results showed that： both the dispersants had increased viscosities of the dispersions, reaching the purpose of dispersing sludge flocculate? After dispersed by sodium hexametaphosphate, both Jiahe and Kailuan clean coal ashes, recoveries were improved within a certain range, but had no regularity; because of the repulsion between CMC and the collector, the clean coal was difficult to float out, though it had better dispersion? So it could not be used as slime-flocculate dispersants of flotation. Key words: slime-flocculate; dispersant; sodium hexametaphosphate; CMC 0引言 精煤浮选过程中，市于前期煤泥水系统中絮凝剂及助滤剂等辅助药剂的加入，使得循环 水中留有残余药剂，此类循环水在用于浮选时会使煤泥絮团，于浮选不利。基于水煤浆制备 基金项H：创新研究群体科学基金；教育部重大项11 (308011)；创新学者攀登计划(BK2008006)。 作者简介：戚冬伟(1973-),男，，安徽砺山人，硕士，讲师，主要从事精细化工产品研究开发、化学化工教 学工作。主要研究方向：煤泥水处理,褐煤表面化学。Ema订：qidongweil973@189.cn,Tel: 过程中分散剂的应用原理及效果lM01,考虑在循环水中加入某种分散剂，以期能够有效地分 散煤泥颗粒，使浮选系统中的煤粒能够更好地与浮选药剂作用，从而达到较好的浮选效果。 首先对分散剂加入后的煤泥水体系粘度进行测量，初步表征其分散效果。对加入分散剂处理 的煤泥进行浮选，以所得精煤