Ni-Ti形状记忆合金纤维相变的电阻特性研究.docVIP

Ni-Ti形状记忆合金纤维相变的电阻特性研究 徐磊王瑞张淑洁 (天津工业大学纺织学院,天津 300160 摘要相变温度是决定形状记忆合金纤维的加工与使用的重要性能参数。以Ni-Ti合金纤维为例,为研究其相变过程中温度与电阻之间的关系,基于纤维内部马氏体生长模型和电阻的混合定律,建立了Ni-Ti合金的电阻特性模型,研究了自由状态下Ni-Ti纤维电阻率与温度之间的关系。在实验过程中,设计电阻法温度测量装置及信号采集系统,对自由状态下的Ni-Ti 纤维进行测试,通过对纤维电阻率-温度曲线求导,寻找纤维电阻率-温度曲线上的拐点,测得Ni元素质量分数为60.45%的Ni-Ti纤维试样的四个相变温度分别为M s=34.4℃,M f=25.6℃,A s=39.4℃,A f=51.1℃,结果表明:相变温度可通过电阻率-温度导函数准确标定;与常规的DSC法测试相比,测试纤维电阻更容易消除马氏体相变过程中中间相的干扰,因此能够准确地探测Ni-Ti合金纤维的相变,并标定其相变温度。 关键词Ni-Ti形状记忆合金;纤维;相变;电阻特性;信号采集 中图分类号:TP242文献标志码 Electrical Resistance Properties Of Ni-Ti Shape Memory Alloy Fiber In Phase Transformation XU Lei, WANG Rui, ZHANG Shujie (School of Textiles, Tianjin Polytechnic University, Tianjin 300160, China Abstract Phase transition temperatures are the key parameters that decide the processing and operating temperatures. In this paper, the phase transformation of Ni-Ti shape memory alloy fiber was adopted as the research object. An constitutive relationship between the resistivity and temperature was derived by l ogistic’s martensite volume growth model and mixing rule. The electrical resistence property of a Ni-Ti fiber under free state was described. In the experiment process, a signal acquisition system is established to measure the resistance and temperature of the Ni-Ti fiber. By the derivation of resistance-temperature curves and the mark of the inflection points in the resistance-temperature curve, the measured phase transition temperatures of the fiber sample with Ni mass fraction of 60.45% are Ms = 34.4 ℃, Mf = 25.6 ℃, As = 39.4 ℃and Af = 51.1℃, respectively. The result shows that the phase transition temperatures can be signficantly identified in the derivative curve of resistivity –temperature. Compare with the DSC testing method, the electrical resistance method is easier to eliminate the interference phase in the martensite transformation, thus can detect the fiber phase transformation and identify the phase transformation temperatures more accurately. Key words Ni-Ti shape memory allo