Autolab交流阻抗拟合方法简介.pptVIP

Electrochemical Impedance Spectroscopy Review of ac circuits A purely sinusoidal voltage can be expressed as Where ω is the angular frequency, which is 2π times the conventional frequency in hertz. The current lags the voltage, it can be expressed generally as Where φ is a phase angle. Review of ac circuits A pure resistance R, E=IR, where the phase is zero. A pure capacitance C, Where Xc is the capacitive reactance, 1/ωC A comparison of R and Xc shows that Xc must carry dimensions of resistance, but the magnitude of Xc falls with increasing frequency. Electrochemical Impedance Spectroscopy Review of ac circuits Components along the ordinate are assigned as imaginary and along the abscissa are real, thus, we handle these parameters mathematically as “real” or “imaginary”. A voltage E is applied across R and C Where Z=R-jXc, called the impedance. Review of ac circuits The magnitude of Z and phase angle are given by the following, respectively The impedance is a kind of generalized resistance. The phase angle expresses the balance between capacitive and resistance components in the series circuit. For a pure resistance, φ=0; for a pure capacitance, φ=π/2; and for mixtures, intermediate phase angles are observed. * Electrochemical Impedance spectroscopy 理论 欧姆定律给出直流电位和直流电流的简单关系: ? E = i R (1) 当有交流参与时，关系式为: ? Eac = iac Z (2), 其中Z为阻抗 Working Electrode Counter Electrode Reference Electrode POTENTIOSTAT GALVANOSTAT Diff. ampl. sense D E F G A B C H I Electrochemical Cell + - + - + - + - + - + - + - + - + - + - WE CE RE POTENTIOSTAT GALVANOSTAT Diff. ampl. s D E F G A B C H I + - + - + - + - + - Solution Resistance Capacitor double layer D E + - + - + - + - + - Polarization Resistance FRA: Frequency Response Analysis Potentiostatic or galvanostatic measurements Resistance: Z R = E I F = 0 o Capacitance: Z C = 1 w I E F = - 90 o Rsol Rct Cdl  D E F HIGH FREQUENCY LOW FREQUENCY Bode图: lg(Z)