浆料的固相含量对注凝成型氧化锆增韧氧化铝陶瓷的影响.docVIP

　第32卷第9期硅酸盐学报 Vol . 32, No . 9　2004年9月 JOURNAL OF THE CHINESE CERAMIC SOCIETY September , 2004 简　　报 　浆料的固相含量对注凝成型氧化锆增韧氧化铝陶瓷的影响 焦宝祥1,2, 丘　泰1, 李纯成1, 沈春英1, 徐　洁1 (1. 南京工业大学材料学院, 南京　210009; 2. 盐城工学院材料系, 江苏盐城　224003 摘　要:研究了浆料的固相体积分数对注凝成型氧化锆增韧氧化铝(zirconia 2toughened alumina , ZTA 生坯和烧结样品物理力学性能的影响。实验所用Al 2O 3和ZrO 2的质量比为80∶20。用压汞法分析了生坯的孔结构, 结果表明:高固相体积分数浆料制备的生坯孔结构呈双峰分布。 SEM 和XRD 研究显示了高固相体积分数浆料制备的烧结体具有结构致密、ZrO 2分布均匀和t ZrO 2含量高等特点。采用55%固相体积分数 的桨料制备的坯体, 经1600℃烧结2h 后,ZTA 样品的抗弯强度和断裂韧性分别达631. 5MPa 和7. 64MPa ?m 1/2。关键词:氧化锆增韧氧化铝; 性能; 注凝成型; 孔结构; 微观结构中图分类号:TQ174. 758　　文献标识码:A 文章编号:0454 5648(2004 09 05 EFFECT OF SOL ID V OL UME FRACTION OF SL OF ZIRCONIA -T OUGHENE D AL UMINA Y GE LCASTING JIA O B 1Tai 1; L I 1; S HEN Chunying 1; XU Jie 1 (1. College of , Nanjing University of Technology , Nanjing 　210009; 2. Department of , Y ancheng Institute of Technology , Y ancheng 　224003, Jiangsu , China Abstract :The effect of solid volume fraction in slurries on physico 2mechanical properties was investigated for zirconia 2toughened alu 2mina (ZTA green and sintering bodies prepared by gelcasting process. The mass ratio of Al 2O 3and ZrO 2was 80∶20in experiment. The pore structures of green bodies were analyzed with the mercury intrusion method. The results indicate that pore distribution of green b od 2ies prepared by slurries with high s olid v olume fraction a ppears d ouble peaks. SEM photographs and XRD patterns show that sintered sam ples made by slurries with high s olid v olume fraction have a higher densification structure , hom ogeneous distribution of Z rO 2particle and higher content of t Z rO 2phase. The bending strength and fracture toughness of the ZT A ceramics prepared by the slurry with 55%s olid v olume fraction and sintered at 1600℃for 2h can be reached to 631. 5MPa and 7. 64MPa ?m 1/2, res pectively. K ey w ords :zirconia 2toughened alumina ; properties ; gelcasting ; pore structures ; microstructure 　　注凝成型(gelcasting 工艺是20世纪90年代以来出现并迅速发展的一种新的胶态成型工艺[1, 2]。该成型工艺设备简单, 成型的坯体密