Glass-ceramic LiFePO4 for lithium-ion rechargeable battery锂离子蓄电池用玻璃陶瓷.pdf

Solid State Ionics 206 (2012) 78–83 Contents lists available at SciVerse ScienceDirect Solid State Ionics journal homepage: www. else vi er. com/ locate/ssi Glass-ceramic LiFePO4 for lithium-ion rechargeable battery T. Nagakane a, H. Yamauchi a, K. Yuki a, M. Ohji a, A. Sakamoto a,⁎, T. Komatsu b, T. Honma b, M. Zou c, G. Park c, T. Sakai c a Nippon Electric Glass Co., Ltd., 2-7-1 Seiran Otsu, Shiga 520-8639, Japan b Nagaoka University of Technology, 1603–1 Kamitomioka Nagaoka, Niigata 940–2188, Japan c National Institute of Advanced Industrial Science and Technology, 1-8-31 Midorigaoka Ikeda, Osaka 563-8577, Japan a r t i c l e i n f o a b s t r a c t Article history: Glass-ceramic LiFePO4 was synthesized through the crystallization of glass powder prepared by melting low- Received 9 June 2011 cost raw materials in ambient air. To obtain the homogeneous precursor glass, the addition of a small amount Received in revised form 14 October 2011 of Nb2O5 was effective. Ferric ions in the precursor glass were reduced and precipitated as LiFePO4 through Accepted 15 October 2011 the heat treatment of a mixture of the glass powder and a carbon source. The obtained glass-ceramic particles Available online 16 November 2011 contained a LiFePO4 crystalline phase and a carbon-containing surface amorphous layer with a thickness of Keywords: about 20 nm. A lithium-ion rechargeable battery fabricated with the