KH550改性六方氮化硼杂化PBS薄膜的性能.doc

复合材料学报 Acta Materiae Compositae Sinica DOI： 六方BN/聚丁二酸丁二醇酯耐热性复合膜的制备及性能 张 敏*收稿日期：201 收稿日期：2014-09-11；录用日期：2014-12-03；网络出版时间： 网络出版地址： 基金项目：高等学校博士学科点专项科研基金(20126125110001)；高分子材料工程国家重点实验室(四川大学)开放课题基金资助( KF201101) 通讯作者：张敏，女，博士，教授，博士生导师，主要从事可生物降解材料的合成和降解机理研究。 yanjiushi206@163.com. 引用格式：张敏，张驰，许小玲，等. 六方BN/聚丁二酸丁二醇酯耐热性复合膜的制备及性能[J].复合材料学报, 2015, 32(x): xxx-xxx. Zhang Min, Zhang Chi, Xu Xiaoling, et al. Preparation and properties of micron hexagonal BN/ poly(butylene succinate) thermal endurance composite films[J]. Acta Materiae Compositae Sinica, 2015, 32(x):xxx-xxx. (陕西科技大学，教育部轻化工助剂化学与技术重点实验室，陕西 西安710021) 摘要：采用偶联剂KH550改性微米六方氮化硼(h-BN)，对聚丁二酸丁二醇酯(PBS)进行共混改性，通过熔融共混与开炼压延工艺制备出具有较高耐热性的h-BN-KH550/PBS复合膜。并对h-BN-KH550粒子结构，复合膜的力学性能、聚集态结构、断面形貌、结晶性能、热稳定性进行测试和表征。结果表明：与PBS相比，h-BN-KH550/PBS复合膜力学性能得到改善，当KH550与h-BN质量比为2:50，h-BN-KH550与PBS质量比为3:50时，综合力学性能最优。进一步研究发现h-BN-KH550粒子可在在PBS中均匀分散；PBS结晶过程中，h-BN-KH550作为成核剂，使PBS的结晶速率加快，结晶度增大。此外，h-BN-KH550/PBS复合膜热稳定性显著提高，h-BN-KH550与PBS质量比为3:50时，复合膜热分解过程中质量损失5%、10%、50%的温度(T5d、T10d、T50d)和热分解峰值温度(Tp)依次提高了30.0℃、22.6℃、9.5℃和10.0℃。 关键词：聚丁二酸丁二醇酯；六方BN；复合膜；KH550；热性能 中图分类号：TB332;TQ316.6+2 文献标志码：A Preparation and properties of micron hexagonal BN/Poly(butylene succinate) thermal endurance composite films ZHANG Min *1, ZHANG Chi, XU Xiaoling, MIAO Nina, WANG Lei (Key Laboratory of Auxiliary Chemistry ＆ Technology for Chemical Industry, Ministry of Education, Shaanxi University of Science ＆ Technology, Xian 710021, China) Abstract: The micron hexagonal BN was treated with coupling agent KH550, and blended with poly(butylene succinate) (PBS) to modify PBS. The high thermal endurance h-BN-KH550/PBS composite films were prepared through melt blending and rolling mill process. The crystal types, fracture morphologies, thermal and mechanical properties of the h-BN-KH550/PBS composites films were investigated. The results reveal that the mechanical properties of h-BN-KH550/PBS composite films are greatly improved compared with PBS. Wh