浮法玻璃复合法在线镀双层膜的研究.docVIP

　第33卷第11期硅酸盐学报Vol.33,No.11　2005年11月J OURNAL OF T H E CHIN ESE CERAMIC SOCIET Y November,2005简　　报　　　浮法玻璃复合法在线镀双层膜的研究 赵洪力1,2,刘起英3,4,韩　冰1,张福成1,2 (1.燕山大学材料科学与工程学院;2.河北省亚稳材料制备技术与科学重点实验室;3.秦皇岛开发区蓝光玻璃 新技术有限公司;4.浙江大学蓝星新材料技术有限公司,秦皇岛　066004 摘　要:在浮法玻璃生产线的锡槽内和玻璃板面温度600℃的退火窑区分别采用电化学方法和化学气相沉积法,在浮法玻璃表面在线镀膜,制备了双层膜。对双层膜的光谱性能、耐磨性和耐酸碱性进行了测试。用扫描电镜、原子力显微镜对膜的表面形貌和断面进行了观察。结果表明:这种在线复合法制备的双层膜增强了单层膜的阳光控制功能,同时可赋予玻璃多种需要的颜色。双层膜光谱性能和颜色特征可以通过改变工艺条件得到调节。膜层表面均匀,耐磨性、耐酸碱性良好。 关键词:浮法玻璃;在线镀膜;双层膜;化学气相沉积;电浮法;阳光控制镀膜玻璃 中图分类号:TQ171.721　　文献标识码:A　　文章编号200511142605 STU DY OF BI2LAYER FI LM ON FLOAT G LASS B Y COMPOUN D TECHN OLOG Y ON2L INE Z HA O Hongli1,2,L IU Qi y ing3,4,HA N B ing1,Z HA N G Fucheng1,2 (1.College of Materials Science Engineering,Yanshan University;2.Key Laboratory of Metastable Materials Science Technology,Hebei,Yanshan University;3.Languang G lass New Technology of Qinhuangdao Development Z one Ltd.;4.Lanxing New Material Technology Company of Zhejiang University,Qinhuangdao　066004,China Abstract:Chemical vapor deposition and electrochemistry were respectively used for on2line depositing a bi2layer film on float glass in a float bath and a lehr gap where the glass surface is600℃.The spectrum properties,anti2wear and chemical stability of the bi2layer film were measured,and in addition the surface morphology and a cross2section of the bi2layer film were analyzed by scanning electron microscopy and atomic force microscopy.The results show that the bi2layer film prepared by the com2 pound technique on2line improves the solar control function of single films and endows the glass with many needed colors.The spectrum properties and colors can be adjusted by changing the technical conditions.The uniform surface of the film has excel2 lent stability against abrasion and erosion of acid and alkali. K ey w ords:float glass;coated on2line;bi2layer film;chemical vapor deposition;electro float;solar control coated glass 　　在平板玻璃上进行大面积镀膜的工艺分为离线镀膜技术和在线镀膜技术,两大技术各有特点。离线的磁控溅射镀膜技术因其质量稳定、品种丰富和新产品开发较为方