水性环氧树脂固化剂的制备与改性.docVIP

第41卷第11期2013年6月 广州化工 Guangzhou Chemical Industry Vol.41No.11 June.2013水性环氧树脂固化剂的制备与改性 周子鹄1,贾元峰2,惠海军2,朱婧2,刘刚1,孙再武1,刘娅莉2 (1广州秀珀化工有限公司,广东广州324401;2湖南大学化学化工学院,湖南长沙410082 摘要:采用三乙烯四胺(TETA/三羟甲基丙烷三缩水甘油醚(TMPEG摩尔比为6∶1,反应温度为60?、反应时间3h的工艺条件下首先合成TMPEG－TETA加成物,然后用TMPEG－TETA加成物与环氧树脂物质的量比为2∶1扩链,最后用苯基缩水甘油醚封端,最终得到粘度较低的透明水溶性固化剂。固化剂可常温下固化环氧树脂,固化膜具有良好的光泽度、硬度、附着力及抗冲击性能。研究还发现固化剂中添加适量胺基硅氧烷能提高固化膜的光泽度和硬度,可有效提高涂膜的耐磨性。 关键词:三羟甲基丙烷三缩水甘油醚;水性环氧树脂涂料;胺固化剂;三乙烯四胺(TETA 中图分类号:TQ630.7文献标识码:B文章编号:1001－9677(201311－0114－03 The Preparation and Modification of Waterborne Epoxy Curing Agent ZHOU Zi－hu1,JIA Yuan－feng2,HUI Hai－jun2,ZHU Jing2,LIU Gang1,SUN Zai－wu1,LIU Ya－li2 (1Guangzhou Supe Chemical Co.,Ltd.,Guangdong Guangzhou511495; 2College of Chemistry and Chemical Engineering,Hunan University,Hunan Changsha410082,China Abstract:Firstly a TMPEG－TETA adduct was synthesized by trimethylolpropane triglycidyl ether TMPEG and Triethylene－tetramine(TETAin the molar ratio6∶1,at60?,reacting for3h.Then the TMPEG－TETA adduct was reacted with epoxy(EPin molar ratio2/1.Finally the secondary amine of TMPEG－TETA and Epoxy resin828 adduct was closed by Phenyl Glycidyl Ether as a termination agent of adduct at the same reaction condition.The waterborne epoxy coating with this curing aagent had good gloss,hardness,adhesion and good impact resistance.The effects of amino siloxane KH－550and the in epoxy curing agents on the properties of waterborne epoxy coatings were studied.The results showed that appropriate amine silicone improved the gloss and hardness of the epoxy coating. Key words:trimethylolpropane triglycidyl ether;waterborne epoxy coating;curing agent;triethylene－tetramine (TETA 环氧树脂具有优异的力学性能,粘结性能,加工性能以及耐腐蚀性能,已经在工业上获得广泛的应用,但环氧树脂本身不会固化,只有加入固化剂,并在一定的条件下进行固化反应,形成立体的网状结构,才能呈现出优良的性能[1]。因此,固化剂在环氧树脂的应用中是不可缺少的。环氧树脂固化剂中最重要的是胺类固化剂,占全部固化剂的71%,因此胺类固化剂改性的研究尤为重要。水性环氧树脂涂料固化剂多采用改性多元胺,如酰胺基胺类、聚酰胺类、聚酰胺加成物和环氧－胺加成物等[2－3],其中环氧－多胺加成物较适合室温固化的水性环氧涂料,其制备方法多为对多胺类固化剂的扩链、接枝、采用挥发性有机酸去中和成盐方法,以降低固化剂活性、延长施工期限[4]。这种固化剂由于加入了一定量的有机酸,因而影响了涂膜的耐腐蚀性能,不适用于