AOAC 991.04 AOAC Official Method 991.04 DDT-国外标准规范.pdfVIP

AOAC Official Method 991.04 DDT in Technical Products and Pesticide Formulations Gas Chromatographic Method First Action 1991 CIPAC-AOAC Method (Applicable to DDT technical and its water-dispersible powder, emulsifiable concentrate, and dustable powder formulations.) Results of the interlaboratory study supporting the acceptance of the method: Technical product: s = 0.84; s = 0.87; RSD = 1.12%; RSD = 1.16% r R r R Water-dispersible powder: s = 0.56; s = 0.81; RSD = 1.02%; RSD = 1.48% r R r R Emulsifiable concentrate: s = 0.13; s = 0.40; RSD = 0.68%; RSD = 2.08% r R r R Dustable powder: s = 0.07; s = 0.15; RSD = 0.82%; RSD = 1.80% r R r R A. Principle Test portions are dissolved in CHCl with 2,2-dinitrobiphenyl added as internal 3 standard. p,p -DDT content is determined by gas chromatography with flame ionization detection and quantitation by peak area measurements. B. Safety Acute oral LD of p,p -DDT for rats is 113-118 mg/kg [The Pesticide Manual 50 (1987), 8th Ed., British Crop Protection Council, Thornton Heath, United Kingdom]. Use CHCl only with adequate ventilation. Avoid contact of CHCl with eyes, skin, 3 3 or clothing. (See also safety note on CHCl .) 3 C. Apparatus and Reagents (a) Gas chromatograph.-With flame ionization detector and suitable for on-column injection. Operating conditions: temperatures-injector 250°C, detector 275°C, column