无机化学课件10. Group VIIA VIIIA.pptxVIP

Halogens group 17;Symbol;Physical Properties：;F2 Cl2 Br2 I2;F2+NaOH ? NaF+OF2↑+H2O ;Proportionation：;2KMnO4+2KF+10HF+3H2O2 == 2K2MnF6+8H2O+3O2 ;Lab：;Br2(l);@ Ambient T，colorless, pungent; in dilute solution：;HCl;Hydrolysis of halides; Intermolecular Forces: Dispersion Force non-polar Easily dissolvable in organic solvents, not much in H2O ;-;Molecular Orbital Theory – I3-;The linear I3- molecule, with D∞h symmetry, is an example of 3c-2e bonding. I3- has 22 valence electrons and all but one of the MOs are filled (only the su* orbital is empty).