稿件纳米粒度与ZETA电位.pptVIP

核心部件: 相关器 最新一代相关器 4000通道, 最小采样时间为25纳秒 (前一代512通道,最小采样时间为50纳秒) 可提供更准确的结果 ..... * 非侵入式背散射 - NIBS 专利 新型专利技术-- 非侵入式背散射专利(NIBS) NIBS - Non-Invasive Back-Scatter 检测角度: 173° 可大大提高信噪比,灵敏度比90度角提高50倍(因为背景噪音主要为大粒子,信号主要在小角度 可自动调节样品池位置,在高浓度时可消除多重散射,所以样品浓度范围可以很宽:0.1PPM-40% ..... * NIBS(非入侵式背散射)技术 光纤探测 精确确定样品池内的测量部位 增大散射体积 提高测量粒径上限 测量低浓度小颗粒的灵敏度增高 0.1mg/mL的溶解酵素 (14,400Da) 测量高浓度 乳液不用稀释 40wt%的硅胶 可自动调节测量位置以减低吸收与提高信噪比 ..... * Cholesterol387Da, 20mg/ml Hydrodynamic diameter = 0.64nm ..... * ZETA POTENTIAL ..... * WHAT IS ZETA POTENTIAL? Zeta 电位是一个粒子在特定介质中获得的全部电荷，它不同与表面电荷 Zeta电位可判断分散体系的稳定性 pH, 盐浓度和其它添加剂可改变分散体系中粒子的Zeta电位，由此可研究分散体系的稳定性的机理。 Zeta电位越高，稳定性越好。 ..... * { Stern layer ZETA POTENTIAL Within the diffuse layer is a notional boundary (the slipping plane) within which the particle acts as a single entity The potential at this boundary is the ZETA POTENTIAL Slipping plane Diffuse layer - -100 0 mV Distance from particle surface Surface potential Zeta potential Particle with negative surface charge ..... * ZETA POTENTIAL 主要检测方法: 1.声波方式: a.测的是动态迁移率,需经换算才可得到,但换算需大量参数: Sound speed ,Heat capacity,Density,Viscosity , Volumetric thermal expansion coefficient,particle size b. 样品与介质的密度一定要差别大,不然测不出,所以这种方法不适合一般乳液,微乳液等,但适合于矿物,陶瓷浆料等 2.电泳方式 ..... * How is it Measured (Electrophoresis) - - - - - - - - + - ELECTRODE ELECTRODE ELECTRICAL ATTRACTION VISCOUS DRAG = microns / sec Volts / cm Mobility = velocity electrical field strength Particle ..... * The Zeta Principle + - Negatively Charged Particle ..... * 两种样品池 + - + - Capillary cell Dip cell Dip cell vs Capillary cell ..... * How is it Measured? + - Dip cell Whilst the disposable dip cell looks attractive, the following drawbacks are immediately apparent. In order to maintain uniform electric fields, the electrodes must be relatively close together and of large cross sectional area. Volts applied generates a current. Volts X Amps = Watts = heating. The temperature must not change