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Pseudomorphic Synthesis of Micelle-Templated Silica (MTS) for Next Generation HPLC Packing Materials Introduction: Pseudomorphism is a term introduced by mineralogist to describe phase transformation that does not change the shape of a material. Pseudomorphic synthesis, assisted by surfactant, for mesoporous pre-shaped silica particles allows to highly ordered narrow mesopore size distribution, the high surface area and pore volume without changing the initial shape of silica particles. The micelle-templated silica (MTS) particle synthesis started a decade ago, and has attracted a lot of interests in academic research for past several years. The MTS materials represent a class of next generation and promising supports for advanced separation processes, such as GC and HPLC. The high specific surface area, high pore volume, and adjustable pore size should improve, respectively, the retention capacity, column permeability, and molecular selectivity. For example, K. Unger has synthesized 10 μm MTS beads with pore diameter ranging from 7 to 9 nm, specific surface area of 900 m2/g, and pore volume of 1.5 mL/g. (Figure from Thierry Martin. etc. in Chem. Mater., 2004, 16, 1725-1732) Pseudmorphic synthesis is done in autoclave at above water boiling temperature, or simply by refluxing a solution containing a base such as NaOH or NH4OH, silica particles, a micelle agent such as cetyltrimethylammonium bromide, and a sAlling agent such as trimethyl benzene in a flask for overnight to several days. After reaction, the micelle and sAlling agents can be removed by either burn-off or solvent extraction. Up to now, most research is still mainly in the academic area, and is focusing on the development of 5 to 10 μm MTS materials. The starting materials are pre-shaped silica with large particle size distribution and Aak mechanic strength. The development of silica particles less than 2 μm has not been successfully developed yet. MTS has superior properties for chromatography, a