高分子材料加工技术专业英语 Step-Growth Polymerization Step-Growth Polymerization.pptVIP

高分子材料加工技术专业英语 逐步聚合 Step growth polymerization 主讲：靳玲 徐州工业职业技术学院 WORDS AND EXPRESSIONS Dimer 二聚体 Trimer 三聚体 Tetramer 四聚体 Pentamer 五聚体 Esterification 酯化 Adipoyl chloride 己二酰氯 Hexamethylene diamine 己二胺 * n n monomer polymer C = C H H H H C C H H H H n When ethylene is polymerized to make polyethylene, the every atom of the ethylene molecule becomes part of the polymer (none gained, none lost) Ethylene Polyethylene Example: H + H2O acid alcohol ester esterification MONOMER diacid dial polyester PET +n H2O STEP GROWTH POLYMERIZATION monomer + monomer = dimer dimer + monomer = trimer dimer + dimer = tetramer trimer + dimer = pentamer n-mer + m-mer = (n+m)mer or Two short chains can react to form longer chain NYLON 6,6 This Cl atom and this H atom don’t end up in the polymer, they split off to form HCl gas. + N-CH2-CH2-CH2-CH2-CH2-CH2-N H H H H Cl-C-CH2-CH2-CH2-CH2-C-Cl O O nylon 6,6 adipoyl chloride hexamethylene diamine HCl + C-CH2-CH2-CH2-CH2-C- O O N-CH2-CH2-CH2-CH2-CH2-CH2-N H H n Step growth polymerization: generally = condensation polymerization——Two short chains can react to form longer chain. monomer disappears much faster molecular weight increase through out the course of the reaction high molecular weight polymer is not obtained until the end of the reaction CONCLUSION QUESTION What is the difference between step growth polymerization and chain growth polymerization ? * WORDS AND EXPRESSIONS Dimer 二聚体 Trimer 三聚体 Tetramer 四聚体 Pentamer 五聚体 Esterification 酯化 Adipoyl chloride 己二酰氯 Hexamethylene diamine 己二胺 * WORDS AND EXPRESSIONS Dimer二聚体 Trimer三聚体 Tetramer[tetr?m?]四聚体 Pentamer[pent?m?]五聚体 Esterification酯化 Terapheyl chloride Ethylene glycol[?eθ??li:n ?ɡlaik?l]?乙二醇 Adipoyl chlor