金纳米粒子形貌控制.pptVIP

Morphology control of au Nanoparticles 十成王刑杨许薛 三员立怀景佳 组军勇帆三祥 Importance of Morphology control Unique and tunable optical, electronic, and catalytic properties of Au nanostructures Promising applications in surface-enhanced spectroscopies, chemical or biological sensing, and the fabrication of nanodevices The properties of Au nanostructures can be tailored by controlling their composition, size, shape, and structure (hollow vs solid) Synthesis of Gold Nanocages Ag nanocubes E3Ag+ Au(l)-+ Au +3Ag() i A simple means of preparing multimetal hollow structures Like a zinc strip in a solution containing Cut ions Ag nanocubes serve as a template for reaction SARAE. SKRABALAK et al Nano, 2008, 2(9), 1760-1769 The mechanism for nanocage formation (I) B 100n E The initial reaction at a high-energy site(surface step point defect, or hole) The pinhole serves as the anode, and then the site for Ag dissolution The mechanism for nanocage formation (l) 200nm E This difference attributed to poly(PVP) (1ll) corners poorly passivated Ag dissolution at (1ll), while Au deposition at the (100) The mechanism for nanocage formation 的8 回3K the galvanic replacement reaction used first to form nanoboxes using the wet etchant Fe(NO3 )3 to selectively dissolve Ag anorattles(A) and multiple-Walled o◎ Nanoshells( B) prepared by replacing the Ag nanocubes I with other Ag nanostructures i Ag deposited on the surface of Au/A nanoshells followed by galvanic 100nm replacement (A, C) D Ag layer deposited on Au/Ag nanoshells followed by galvanic replacement(B, D) SARAE. SKRABALAK et al Nano, 2008, 2(9), 1760-1769 -50 nm Surfactant-Mediated Self-Assembly ofAu Nanoparticles 1-dodecanethiol toluene suspension abha 1.9-nonanedithiol Centrifuging Teflon-lined stainless steel autoclave Ethanol stabilization YXZhang, H C Zeng Langmuir, 2008, 24(8)33740-3746 m 500mm As-synthesized AuNPs TEM Spherical Au aggregates TEM Y X Zhang, HC Zeng Langmuir, 2008, 24(8),3740-3746 ILT Assembly-then-attachment mech