《第六章 疏水材料--超疏水》.pptVIP

第六章 疏水材料--超疏水;1 Wettability; Water contact angle (WCA) larger than 150° and extremely low WCA hysteresis or sliding angle less than 10°.;Sliding angle;A wide spectrum of applications;;;;Water collector? in the desert; ;Antifouling coating; ;Drag reduction;Self-cleaningmaterials;;Antifogging surfaces;局部放大;;;;Cicadas wings;Butterfly wings;;2、 The theoretics of Supperrepellent material;For smooth, flat, uniform solid surface, the relationship between contact angle and surface energy can be described by Yong’s equation (Thomas Young, 1805 ) : 　 cosθ=(γSV –γSL)/ γLV ; Hydrophobic surface;Functional surface;Fluorinated polymer;self-assembly ;;Real solid surface with concave-convex structure;Cosθ*=;Cosθ*=;;;PAN Nano fiber material;;Self-cleaning effect;;;Turning a Surface Super-Repellent Even to Completely Wetting Liquids ;Template method;Etching ; ;Chen等利用纳米球刻蚀的方法首先得到了排列整齐的单层聚苯乙烯 (PS)纳米珠阵列 ,再用氧等离子体处理以进一步减小纳米珠的尺寸从而得到粗糙表面。在其表面覆盖 20nm厚的金膜并用十八硫醇(ODT)进行修饰可以增强其疏水性。通过调整 PS纳米珠的直径 (440-190 nm)可以控制表面接触角的大小 (132-168° )。;;Chemical vapor?deposition;4 Research plan;;;;;;Some questions