The Art of writing reasonable organic mechanism ansinchap1-3有机化学机理书写艺术习题参考答案1-3.pdfVIP

1 ANSWERS TO PROBLEMS IN BODY OF CHAPTER 1. 1.1. The resonance structure on the right is better because every atom has its octet. 1.2. O– O CH2+ CH2 CH2 CH2 C O C O NMe2 NMe2 NMe2 NMe2 NMe2 NMe2 N N N N N H C H C 3 3 N CH2 N CH2 H C H C O O 3 3 the second structure is hopelessly strained 1.3. 2 3 2 O sp O– sp3 CH3 sp CH3 sp sp2 N Ph N sp3 sp2 sp3 sp sp Ph H C CH H C CH O 3 3 3 3 2 3 3 3 sp2 sp all sp2 all sp2 sp sp sp 2