材料热力学答疑课.pdf

材料热力学习题 2014.12.18 4.3 At 400℃, liquid zinc has a vapor pressure of 10-4 atm. Estimate the boiling temperature of zinc, knowing that its heat of vaporation is approximately 28 kcal/mol. Answer: 4.10 The melting point of gold is 1336 K, and the vapor pressure of liquid gold is given by: ln P(atm)=23.716-43522/T-1.222 lnT(K) (a) Calculate the heat of vaporization of gold at its melting point. Answer parts b, c, and d numerically only if the data given in this problem statement are sufficient to support the calculation. If there are not enough date, write “solution not possible.” (b) What is the vapor pressure of solid gold at its melting point? (c) What is the vapor pressure of solid gold at 1200 ? (d) What is the heat of fusion of solid gold? Answer: 5.3 Calculate the temperature at which silver oxide begins to decompose into silver and oxygen upon heating: (a) In pure oxygen at P=1 atm (b) In air at Ptotal=1 atm DATA ΔH for Ag O=-7300 cal/mol f 2 Standard Entropics at 298 K [cal/mol K] Ag O 29.1 2 O 49.0 2 Ag 10.2 Assume that ΔCp=0 for the decomposition reaction. Answer: 5.6 The following equilibrium data have been determined for the reaction: NiO(s)+CO(g)→Ni(s)+CO (g) 2 -3 T(ºC) K( ×10 ) 663 4.535 716 3.323 754 2.554 793 2.037