氧化锌法脱硫过程中臭氧强化氧化亚硫酸锌基础研究.docxVIP

氧化锌法脱硫过程中臭氧强化氧化亚硫酸锌的基础研究 曹雪娇，张廷安收稿日期：2019-9- 收稿日期：2019-9-17 基金项目：国家自然科学基金（U1760120） 通迅作者：张廷安（1960-），男，教授，博士生导师，主要从事自蔓延冶金，冶金反应工程，高压湿法冶金等方向的研究，E-mail:zta2000@163.net. （东北大学，多金属共生矿生态化冶金教育部重点实验室，辽宁沈阳110819） 摘要：氧化锌法脱除低浓度二氧化硫过程中副产物亚硫酸锌的氧化回收利用是影响脱硫工艺发展的重要步骤，同时也是解决脱硫系统设备管道结垢堵塞问题的关键，本文提出利用臭氧强化氧化亚硫酸锌生成可溶性硫酸锌的新方法。研究了亚硫酸锌初始含量、搅拌转速、臭氧流量、溶液初始pH以及温度对臭氧氧化亚硫酸锌的影响。结果表明氧化过程中溶液的pH先增加后降低，溶液中锌离子浓度随氧化过程的进行而线性增加。亚硫酸锌臭氧氧化速率随初始亚硫酸锌含量的增加先增加后降低，随搅拌转速的增加而增大，随臭氧流量的增加先增加后减小，随溶液初始pH的增加而增加，温度对氧化速率的影响较小。研究结果为氧化锌法高效脱硫及副产物的回收利用提供了理论基础。 关键词：臭氧；亚硫酸锌；氧化速率；强化氧化 Basic research on the enhanced oxidation of zinc sulfite by ozone in the zinc oxide desulfurization process CAO Xuejiao, ZHANG Tingan, LIU Yan, ZHANG Weiguang, LI Simin, LV Guozhi, HAN Xiuxiu (Northeastern University, Key Laboratory of Ecological Metallurgy of Multi-metal Intergrown Ores of Ministry of Education, Liaoning Shenyang, 110819) Abstract: Oxidation recovery and utilization of by-product zinc sulfite in the process of removing low concentration of sulfur dioxide by zinc oxide is an important step. At the same time, it is also the key to solving the problems of fouling and plugging of equipment pipelines caused by low oxidation rate of desulfurization system. A novel method of ozone-enhanced oxidation process to oxidize the zinc sulfite and to form soluble zinc sulfate was proposed in this paper. Effects of initial concentration of zinc sulfite, stirring speed, ozone flow rate, initial pH, and temperature were investigated. The results showed that the pH of the solution increased first and then decreased during the oxidation process. The concentration of zinc ion increased linearly with the oxidation time during the process. The oxidation rate increased first and then decreased with the initial zinc sulfite concentration increased. With the stirring speed increased, the oxidation rate increased. The oxidation rate increased first and then decreased with the ozone flow rate increased. With the initial pH increased, the oxidation rate increa