现代无机化学：超分子化学与晶体工程基础-柔性配位聚合物.pdfVIP

7. 柔性配位聚合物 Flexible coordination polymers 1 咪唑基阴离子及二价d10金属组装的SOD微孔材料：[Zn(mim) ] ⋅xsolvent SOD Zinc 2-methylimidazolate 2 n Me Zn2+ + N N SOD-[Zn(mim) ] (MAF-4) Free Diameter 11.4 Å 2 Window 3.3 Å solvent accessible area 47.0% Hydrophobic Angew. Chem. Int. Ed. 2006, 45, 1557. 2 咪唑三氮唑 R Zn2+ + N N SOD structure with active N atoms N Free Diameter 11.6 Å SOD-[Zn(mtz) ] (MAF-7) Window 4.1 Å 2 Hydrophilic Adv. Mater . 2011, 22, 1268 3 Surface modification Cage d 11.4 Å Window d 3.2 Å MAF-4 Void = 49.8% Me SOD-[Zn(mim) ] 2 N N Hydrophobic Zn2+ + Me MAF-7 N N SOD-[Zn(mtz)2] N Hydrophilic Cage d 11.6 Å Window d 3.4 Å Void 51.7%