辽宁省典型污染场地土壤多环芳烃组成特征研究.docxVIP

辽宁省典型污染场地土壤多环芳烃组成特征研究 Abstract： In order to determine the compositional characteristics of polycyclic aromatic hydrocarbons （PAHs） in soil of typical contaminated sites in Liaoning Province， more than 1000 soil samples from six typical contaminated sites， including one manufactured gas plant site and five atmospheric precipitation affected sites， were collected and analyzed. The results showed that the contents of low-ring （2-， and 3-ring） PAHs and high-ring （4- to 6-ring） PAHs in the manufactured gas plant site soil were both high， while high-ring PAHs dominated in soil of atmospheric precipitation affected sites. The PAHs with higher rate of over-standard in both types of sites were the same， i.e.， benzo（a）pyrene， benzo（a）anthracene， dibenzo（a，h）anthracene， and benzo（b）fluoranthene. The major high-ring PAHs had good correlation ships， and the correlation coefficient between benzo（a）pyrene and other three high-ring PAHs were generally higher than 0.94. It was found that other PAHs were below the standards when the benzo（a）pyrene in the soil was below the standard， indicating that benzo（a）pyrene could be used as an indicative contaminant for such sites. The results can provide a reference for the investigation and evaluation of similar sites. Key Words： Contaminated sites; Polycyclic aromatic hydrocarbons; Benzo（a）pyrene 1 背景 多环芳烃（Polycyclic Aromatic Hydrocarbons PAHs）因具有“三致”效应和检出率较高成为最受关注的土壤污染物之一[1-2]。PAHs是石化燃料不完全燃烧的产物，土壤中的PAHs可来自石油开采、炼焦生产和大气沉降。辽宁省是我国老工业基地，冬季燃煤供暖期也较长，即使在没有PAHs生产使用历史的场地中也常常检出PAHs。 本研究选择辽宁省典型污染场地，分析土壤中PAHs的组成和相关性特征，识别指示性PAHs，以期对同类场地的调查评估提供参考。 2 材料与方法 2.1 土壤样品 土壤样品来自辽宁省6个污染场地，其中1个为焦化厂场地，其他5个均无明确的PAHs使用历史。场地基本信息见表1。 2.2 多环芳烃检测与数据分析 利用气相色谱-质谱方法检测土壤中14种PAHs [萘、芴、菲、蒽、荧蒽、芘、苯并（a）蒽、?、苯并（b）荧蒽、苯并（k）荧蒽、苯并（a）芘、茚并（1，2，3-cd）芘、二苯并（a，h）蒽、苯并（g，h，i）苝]，执行标准为美国EPA 8270C，检出限为0.1mg/kg。检测结果与《土壤環境质量 建设用地土壤污染风险管控标准（试行）》（GB *****-2018）第一类用地土壤风险筛选值进行比较，GB *****不涉及的指标，采用美国EPA区域筛选值居住用地筛选值或美国马里兰州居住用地土壤标准进行比较。 3 结果与讨论 3.1 土壤PAHs超标情况