水性涂料用丙烯酸树脂的制备.docxVIP

PAGE PAGE # PAGE PAGE # 水性涂料用丙烯酸树脂的制备 摘要 与传统的溶剂型涂料相比，水性涂料具有价格低、使用安全，节省资源和能源，减 少环境污染和公害等优点，因而已成为当前发展涂料工业的主要方向。 水性丙烯酸烯树 脂涂料是水性涂料中发展最快、品种最多的无污染型涂料。 本实验采用溶液聚合法，以甲基丙烯酸甲酯（MMA）、丙烯酸丁酯（BA）和丙烯 酸（AA）为单体，以正丁醇为溶剂，过氧化苯甲酰（BPO）为热引发剂，制得了水性 丙烯酸树脂。分析了反应温度、时间，单体、引发剂和中和剂用量对水性丙烯酸树脂性 能的影响。结果表明合成水性丙烯酸树脂的最佳工艺条件为： 丙烯酸AA为单体总摩尔 质量的12.5%,甲基丙烯酸甲酯（MMA）:丙烯酸丁酯（BA）为1:1,引发剂用量为单 体总摩尔质量的0.5%,反应温度为100C,反应时间为3h,中和度为90%。 关键词：丙烯酸树脂，单体，涂料，溶液聚合，合成 The Preparation of Water-based Coating with Acrylic Resin ABSTRACT Compared with the traditional solvent coating, coating with low price The use of safe, save resources and energy, reduce environmental pollution and pollution etc, and thus has become the current development of coating industry the main direction of water-borne acrylic PVC resin paint is water-based coating the fastest growing most varieties in no polluting coatings. This experiment by solution polymerization, with methyl methacrylate (MMA ) , butyl acrylate (BA) and acrylic acid (AA ) as the monomer, with butyl alcohol as the solvent and benzoyl peroxide ( BPO) as the thermal initiator, with water based acrylic resin.Analyzed the reaction temperature, time, monomer initiator and neutralizing agent dosage on the properties of water-based acrylic resin. The results showed that the best process conditions for synthesis of waterborne acrylic resin: Acrylic AA 12.5% of the total molar mass of monomer, methyl methacrylate (MMA ) , butyl acrylate (BA) as 1:1, initiator dosage is 0.5% of the total molar mass of monomer, reaction temperature of 100, the reaction time is 3 h, neutralization degree of 90%. KEYWORDS: acrylic resin, monomer, coating, solution polymerization, synthesis 目录 TOC \o 1-5 \h \z \o Current Document 摘要 ABSTRACT II \o Current Document 1绪论 1 \o Current Document 水性涂料 1 \o Current Document 水性丙烯酸树脂简介 2 水性丙烯酸树脂的概念 2 水性丙烯酸树脂的特点 3 水性丙烯酸树脂的分类 3 \o Current Document 水性丙烯酸树脂的主要合成方法 5 \o Current Document 水性涂料用丙烯酸树脂的研究现状 6 \o Current Document 水性丙烯酸树脂反应机理 8 水性丙烯酸树脂的聚合机理