北京化工大学活性自由基聚合课程.pptxVIP

北京化工大学活性自由基聚合课程会计学1. Iniferter法的历史：1. 引发－转移－终止法（iniferter法） 1982年，日本学者Otsu等人提出了iniferter的概念，并将其成功地运用到自由基聚合，使自由基活性/可控聚合进入一个全新的历史发展时期。 从活性聚合的特征和自由基聚合的反应机理来理解，实现自由基活性/可控聚合的关键是如何防止聚合过程中因链终止反应和链转移反应而产生无活性聚合物链。1. Iniferter法的历史：Dr. Takayuki Otsu is a Professor Emeritus, Osaka City University. In 1956, he found that polymers derived from thiuram disulfides (TD) could induce photopolymerization to give block and graft copolymers. He is the author or coauthor of more than 550 original papers, 120 review articles, 10 books, 30 book chapters, and more than 100 patents. Dr. Otsu was invited abroad to more