银修饰二氧化钛纳米管的可见光催化活性研究.docVIP

Ag掺杂二氧化钛纳米管光催化降解甲基橙及百草枯废水的研究 （姓名：王克鹏） （吉林师范大学坏境工程学院09级3班 吉林四平136000） 指导教师：车广波（副教授） 要:以钛酸四丁酯、硝酸银为原料，利用水热法制备银掺杂二氧化钛纳米 要: 以钛酸四 丁酯、硝酸银为原料，利用水热法制备银掺杂二氧化钛纳米 管,通过处理模拟的甲基橙废水评估其光催化性能。实验探讨了制备条件（掺杂 量，锻烧温度）和光催化条件（添加量、光源、光照时间等）等对其光催化性 能的影响。结果表明：掺杂0.1%Ag（摩尔分数），懒烧温度500°C制得的Ag-TNT 具有较高的光催化活性，添加量为0. lg/L时，经过240min的光照使得甲基橙去 除率达到99. 87 %,动力学分析表明符合动力学一级规律动力学方程为 Ln（Co/CT）=O. 2921X-0. 13382 （R2 =0. 96808） o又进一步用其处理百草枯模拟废 水，结果表明：添加量为0. lg/L时，经过210min的光照使得百草枯去除率达到 99. 87 %,动力学分析表明符合动力学一级规律，动力学方程为 Ln （Co/Ct）二0. 02289X+0. 04752 （R2 =0. 91288）。 关键词：光催化，钛酸盐纳米管，银，掺杂量，温度，加入量 The study of Ag-TNTS photocatalytic degradation of methyl orangeand paraquat wastewater Wang Ke-peng (Class 3 Grade 4 in College of Environmental Engineering, Jilin Normal University,JilinSiping 136000) Directive teacher: CHe Guang?bo(associate professor) Abstract： Abstract: Using tetrabutyl titanate, silver nitrate as raw materials and hydrothermal method to prepare Ag-TNTs, and through the simulation of methyl orange wastewater treatment to evaluate its photocatalytic performance.The experiment discusses the influence on its photocatalytic performance from the preparation conditions (doping quantity, calcination temperature) and light catalytic conditions (adding amount, light source, illumination time, etc.) and so on.The results show that the doped with 0.1% Ag (mole fraction), calcination temperature 500 °C of Ag - TNT has higher photocatalytic activity, adding the amount of 0.1 g/L, and after 240 min of light to achieve 99.87% removal rate of methyl orange, and dynamics equation of dynamics analysis shows that the dynamic level rule for Ln (Co / CT) = 0.2921 X ? 0.13382 (R2 = 0.96808). And when using it to dispose the paraquat simulated wastewater treatment, the results show that adding 0.1 g/L of quantity, after 210 min of light makes the paraquat removal rate reach 99.87%, dynamics analysis shows that the dynamic regularity, dynamic equations for the Ln (Co / CT) = 0.02289 + 0.04752 X (R2 = 0.91288). Key words: ph