锂电池容量分析.docVIP

锂电池容量分析 Analysis of the cause of lithium battety capacity decay Lithium ion battery embedded reaction occurs between two electrodes with different embedding energy, and to obtain the best performance, battery capacity than the two host electrode should keep a balaneed value? In lithium-ion batteries, the balanee of capacity is expressed as a positive mass ratio, namely: Gamma m = m + / - = A xC - / A yC+ Type in C refers to the theory of coulombs capacity of electrode, A x, A y refers to embed the cathode and anode respectively the number of stoichiometric lithium ion. As you can see from the top, the quality of the two poles depends on the amount of coulomb capacity and their respective reversible lithium ions. Generally speaking, the lower quality is less than the use of the negative materia 1. A larger mass ratio may be a safety hazard due to the negative electrode being charged. Overall, the best battery performance is in optimal quality? For an ideal of Li 一 ion battery system, the capacity balance within their cycle does not change, each cycle of the initial capacity to a certain value, but in fact it was much more complex. Any can produce or consume lithium ion or electron side effects could lead to battery capacity balance changes, once the battery capacity balance changes, this change is irreversible, and can be accumulated through many times cycle, serious impact on battery performanee. In lithium ion battery, in addition to lithium ion to take off the embedded REDOX reaction occurs, there are a lot of side effects, such as electrolyte decomposition, active substances dissolved, lithium metal deposition, etc?，as shown in figure Arora [3], such as the process and the half cell discharge capacity attenuation curve contrast, so we can clearly see the battery work when the possibility of capacity attenuation and the reasons, as shown in figure 2. One, a charge The overcharged reaction of the graphite anode: When the battery is overcharged, the lithium ion is e