pp粉表面固相接枝及其表征.docVIP

PP粉表面固相接枝及其表征 ［摘要］　以过氧化苯甲酰(BPO)、过氧化二异丙苯（DCP）为引发剂，用固相接枝法在聚丙烯（PP）粉表面接枝马来酸酐（MAH）。研究了引发剂浓度、单体浓度、反应温度及时间等因素对接枝率的影响，并采用X射线光电子能谱（XPS）与广角X射线衍射（WAXD）对MAH-g-PP的接枝效果和晶态结构进行了表征。 关键词　PP粉　固相接枝　马来酸酐　接枝率 Solid Phase Graft Copolymerization on PP Powder Surface Gu Hui　Chai Chao　Zhang Zhiqian　Wei Yuezhen (Harbin Institute of Technology) ［Abstract］　MAH was grafted on PP powder surface by solid phase graft copolymerization with BPO and DCP as initiators．The grafting degree influenced by factors of the concentration of initiator and monomer，reaction temperature and time was studied．And graft extent and crystal stru