多孔碳材料制备与应用.pdfVIP

摘要 离子液体因为具有绿色环保、不易挥发、稳定性高以及结构设计性强等特点，最几年在 [1] 合成碳材料中的应用引起了人们的广泛关注 。且因多孔碳材料质量轻，法及其相关表征。 稳定性好，耐高温，耐酸碱，无毒性，吸附性好等优点而在多领域中被广泛应用。本文主要 介绍的是以 PEI(聚醚酰亚胺 Polyetherimide)为原料制备离子液体前驱体并制得碳材料的方 法。首先通过向原材料PEI中加入溴乙腈(BrCH)制备离子液体前驱体，向得到的离子液体前 2 驱体中加入二氰胺银[AgN() 进行阴离子交换反应，最后通过活化法得到多孔碳材料。这种 2] 方法的最大优点是有较高的碳产率。 关键词：离子液体、阴离子交换法、多孔碳材料 Abstract In recent years，the application of ionic liquid in the synthesis of carbon materials has aroused extensive attention because of its features, such as green, less volatile, high stability and structural design of characters. And because the porous carbon material with light weight, good stability, high temperature resistance, acid and alkali resistant, non-toxic and good adsorption, it has been used in many fields. This paper mainly introduces the PEI (Polyetherimide) prepared for ionic liquid precursors, methods of carbon materials and related characterization. First by PEI of raw materials to join bromoacetonitrile (BrCH) of 2 ionic liquid precursor preparation, obtained by ionic liquid precursor to join dicyanamide silver [AgN () ] by anion exchange reaction, the activation method of porous carbon 2 materials. The greatest advantage of this method is that there is a high carbon yield. Keywords: Ionic liquid, anion exchange, porous carbon material. 前言 近年来多孔碳材料成为一种新型的快速发展起来的新型材料体系， 在各个领域中的应 用得到了广泛地关注，特别是在能源相关领域的应用。多孔材料因为结构上具有较高的孔隙 率而具有一些相应的优异性能。多孔材料分为多孔金属材料（也就是所谓的泡沫金属）、非 [2] 金属多孔材料（包括多孔陶瓷材料、多孔碳材料、多泡玻璃等） 。因为多孔材料孔道排列 规则且孔道尺寸可以调节控制的优点，大比表面积和大的吸附量，它在大分子催化，吸附及 分离，纳米材料组装等众多领域中具有较为宽泛的应用前景。