锂离子电池硅碳负极的制备工艺及研究.doc

本科毕业设计(论文) 锂离子电池硅碳负极的制备工艺及研究 学 院 专 业 年级班别 学 号 学生姓名 指导教师 年 月 锂离子电池硅碳负极的制备工艺及研究 锂离子电池硅碳负极的制备工艺及研究 摘要 锂离子电池已广泛应用于人类的生活、工作，甚至军事之中，锂离子电池的性能以及其制备工艺成为被广泛研究的问题。本文阐述了锂离子电池的结构特点、工作原理和性能优势，重点介绍了硅-石墨复合负极材料的研究现状、制备工艺以及性能优势。采用高能机械球磨法制备硅-石墨复合负极材料，探讨不同球磨时间、不同煅烧温度等条件对电池负极材料的影响，通过恒流充放电、循环伏安等电化学测试手段对电池进行测试，也利用XRD、SEM等物化性能测试对复合粉体的晶粒大小、结晶状况、微观形貌、物相组成和结合状况进行表征。实验结果表明，制备硅-石墨复合负极材料的工艺参数为：球磨时间12h，煅烧温度650℃。 关键词：锂离子电池，负极材料，硅-石墨复合材料，制备工艺 Abstract Li-ion battery has been frequently used in people’s daily life, work and military activities. Obviously, its performance and preparation technology have been studied. This paper aims to illustrate the structural characteristics, working principle and performance advantages of the lithium-ion battery by focusing on the research study, the working principle and the performance advantages of the silicon - graphite composite cathode materials. In addition, the thesis introduces the preparation of the graphite composite cathode materials by using the high energy mechanical ball-milling method, exploring the different ball milling time, the calcination temperature and other conditions that will affect the negative electrode materials. Moreover, the means of the constant current charge-discharge, cyclic voltammograms and other electrochemical testing methods are applied to test the battery, and the tests of the physical and chemical properties, such as XRD, SEM are applied to characterize the grain size, the crystallization conditions, the microstructure, the phase composition and combination of the compound powder. The experimental result show that the process parameters of the ball-milling time of 12 h and the calcination temperature of 650 ℃, the preparation of silicon - graphite composite can get the satisfying electrochemical properties under the condition of less energy consumption. Keyword：Li-ion batt