三聚氰胺甲醛树脂泡沫的研究.docxVIP

三聚氰胺甲醛树脂泡沬的研究 学位论文完成曰期指导教师签字答辩委员 会成员签字 靑岛科技大学研究生学位论文 Y2039845 三聚氰胺甲醛树脂泡沬的研究 摘要 本文通过三聚氰胺和甲醛溶液在碱性环境下反应制备三聚氰胺甲醛树 脂。通 过调节树脂合成的条件，制备出适合发泡的蜜胺树脂。选择树脂粘度为 75~115Pa-s, 固含量在58.2%~59.7%, 7(TC 时发泡。试验结果表明，蜜胺泡沫的密度随着甲酸、 正戊烷和op-10用量的增加先减小后增加，发泡效果先变好然后变差M。F (三聚氰胺甲醛树脂）泡沫具有良好的阻燃性。MF泡沫的导热系数随着密度的增加先增大后减小，随着温度的增加而增加；MF泡沫的比热随着泡沬密度的增大而减小， 随着温度的升髙而增大。 MF 泡沫具有良好的热稳定性。MF 泡沫在氮气气氛下和空气气氛下只有一个大的分解峰，失重峰温随着升温速率的提髙而提高。MF泡沫在氮气下的热分解活化能在130.22 772.59KJ/mo丨之间，MF泡沫降解峰反应级数的n为0.942。MF 泡沫 在氮气下的热分解活化能在92.79 912.05 kJ/mo 丨之间,MF 泡沫降解峰反应级数的n 为 0.919, 三聚氰胺和甲醛溶液在碱性环境下反应制备三聚氰胺甲醛树脂，然后在一定条件下脱水，然后加入多元醇、表面活性剂和异氰酸酯来制备聚氨酯改性蜜胺发 泡。试验结果表明，MDI (二苯基甲烷二异氰酸酯）改性蜜胺泡沫的泡孔结构最均匀，泡孔尺寸最小，MDI改性泡沫塑料的密度和IPDI (异佛尔 酮二异氰酸酯）改性蜜胺泡沫的密度随着多元醇用量的增加而逐渐减小多。 元醇用量在30%以内 时 MDI 改性泡沫有一定的阻燃性a MDI 改性蜜胺泡沫的热稳定性最好。 计算泡沫的热降解活化能，结果表明随着多元醇用量的增加T，DI (甲苯二异氰酸酯）改性三聚氰胺泡沫的热稳定性降低。试样MDI40的热稳定性优于试样 TDI-40；试样TDI-20的热稳定性优于试样MDI-20。 关键词：三聚氰胺甲醛树脂；泡沫；聚氨酯；热稳定性；阻燃 THE RESEARCH OF MELAMINE-FORMALDEHYDE FOAM ABSTRACT In this paper, melamine-formaldehydc resin was prepared by meiamine and formaldehyde solution 三聚氰胺甲醛树脂泡沫的研究 in the condition of alkaline. The resin was prepared by changing the conditions of synthesizing resin forfoaming. Theresinwasfoamingat70*Cwhenviscosityis 75 115Pa-s, solidcontentis58.2%~59.7%. The result is as following: with the amount of formic acid、n-pentane、and op-10 increasing, the density of MF foam decreases and then increases, the effect of foaming gets better and then worse; MF foam has great flame retardant. The thermal conductivity of MF foam increases and then decreases with the density increasing; decreasing as the temperature increasing. MF foam has great thermal stability. The thermal decomposition of MF foam has only a large peak in nitrogen atmosphere and in air atmosphere. The peak temperature of weight loss increases with the increase of heating rate. The range of the thermal activation energy of MF foam decomposition can be from 130.22KJ/mol to 772.59KJ/mol in nitrogen atmosphere, the reaction order of peak decomposition MF foam is 0.942. T