红外光谱教学课件电子教案全套课件.pptxVIP

IR SpectroscopyWave length ~ 100 mm to 1 mmWave number ~ 100 to 10,000 cm-1Frequency ~ 3 x 1012 to 3 x 1014 HzEnergy ~ 1 kJ to 100 KJ /moleHCl absorptions2885.9 cm-1fundamental band strong5668.1 cm-1first overtone weak8347.0 cm-1second overtone10923.1 cm-1 third overtone13396.0 cm-1fourth overtoneV(r)rPotential Energy CurveHarmonic Approximationm1m2Centre of mass does not move!Vibration of a diatomic moleculeQuantum Mechanics of vibrationTransition Moment = IntegralTransition Moment IntegralSelection RuleMust have an oscillating dipole moment