基础材料和有机材料 (8).pdfVIP

3.2 Substitutional solid solution (1) The formation conditions of substitutional solid solution and the factors affecting solid solubility. 1. The size of ions 2. Type of crystal structure 3. Chemical valence of ions 4. Electronegativity 1. The size of ions r and r represent the radii of solvents and solute ions respectively. 1 2 The relative difference of ion radii denoted as Δr . r r r 1 2  0.15 Continuous solid solution may be formed r