碳纳米管增强铝基复合材料的制备及力学性能研究.docx

? ? 碳纳米管增强铝基复合材料的制备及力学性能研究 ? ? 吴键 邵国森 何代华 陈小红 刘平 张柯 Summary：利用静电自组装和机械搅拌法相结合的工艺制备得到碳纳米管/铝（carbon nanotubes/aluminum，CNTs/Al）復合材料粉体并压坯制成预制块。采用搅拌铸造和热轧相结合的工艺制备得到不同碳纳米管（carbon nanotubes，CNTs）含量的CNTs/Al复合材料。通过扫描电子显微镜（scanning electron microscope，SEM）、X射线衍射仪（X-ray diffractometer，XRD）等表征CNTs/Al的微观组织结构，利用拉伸实验机测试力学性能。通过拉曼光谱仪和傅里叶变换红外光谱仪（Fourier transform infrared spectrometer，FT-IR）对试样进行表征后可知，通过酸化处理成功地在CNTs表面引入了含氧官能团。拉伸试验结果表明：CNTs/Al复合材料的抗拉强度随着CNTs含量的增加先提高后降低;当CNTs质量分数增加到0.3%时抗拉强度达到最大值，为193 MPa;CNTs/Al复合材料的伸长率不断降低，但均为韧性断裂。 Key：碳纳米管;表面改性;铝基复合材料;力学性能 ：TG 146.21??? 文献标志码：A Research on the preparation and mechanical properties of carbon nanotubes reinforced aluminum composites WU Jian，SHAO Guosen，HE Daihua，CHEN Xiaohong，LIU Ping，ZHANG Ke （School of Materials Science and Engineering，University of Shanghai for Science and Technology，Shanghai 200093，China） Abstract： Carbon nanotubes/aluminum （CNTs/Al）composite powders were prepared by the combined technology of electrostatic self-assembly and mechanical stirring method，and pressed into preforms. CNTs/Al composites with different carbon nanotubes （CNTs）contents were prepared by the combined technology of stirring casting and hot rolling. The microstructure of CNTs/Al was characterized by scanning electron microscope （SEM）and X-ray diffractometer （XRD），and the mechanical properties were measured by tensile testing machine. After the samples were characterized by Raman spectroscopy and Fourier transform infrared spectrometer （FT-IR），it can be known that the oxygen-containing functional groups are successfully introduced into the surface of CNTs by acidification. The tensile test results show that the tensile strength of CNTs/Al composites first increases and then decreases with the increase of CNTs content. When the mass fraction of CNTs increases to 0.3%，the tensile strength reaches the maximum value of 193 MPa. The elongations of CNTs/Al composites decrease continuously，but they all show ductile fracture. Keywords： carbon nanotub