HDMO1草酸二甲酯合成催化剂的中试报告.pdf

HDMO-1草酸二甲酯合成催化剂的中试报告 钱胜涛;肖二飞;刘华伟;刘应杰;雷军;吕明;孔渝华;王先厚 【摘要】The effects of space velocity, CO/ MN ratio, reaction pressure and hot spot temperature on the HDMO-1 dimethyl oxalate synthesis catalyst activity and product selectivity were investigated in a 300 t/ a coal-to ethylene glycol pilot plant. MN conversion of higher than 85% , DMO selectivity of 98% , DMO space time yield of 672 g/ L·h could be acquired under the reaction conditions of 131 ℃, 3 000 h -1 , 0. 35 MPa(g), CO/ MN =2. 0 and MN~ 9% , which exceeded that of the laboratory scale result. During the pilot test of