天然气直接高效转化甲烷的研究进展.docxVIP

天然气直接高效转化甲烷的研究进展 自然之声和爆发之声，以及metnam作为主要受害者，是运输和压缩能量的再生家素。 Compared to the thermocatalytic routes,the electrocatalytic route for converting methane into chemicals exhibits obvious merits Herein,we report a porous nickel-based hollow fiber electrode comprising a Ni O active layer on the surface(denoted as Ni O@Ni HF)for electrocatalytic methane conversion reactions.The hollow-fiber-type electrode possesses compact three-dimensional geometry,which provides a large area and three-phase boundary for methane electrooxidation.A methane gas flow enters a Ni-based hollow fiber from one end while the other end is sealed by epoxy resin;thus,excurrentmethane must pass through the Ni O/Ni interface with numerous pores in a 0.1 mol/L aqueous Na OH solution,as shown in Scheme 1.The products,methanol and ethanol,are efficiently generated at the Ni O@Ni HF anode with faradaic efficiencies for CH The synthesis of Ni O@Ni HF composites is mainly divided into two steps:(1)preparation of Ni hollow fiber(Ni HF),which involves an improved phase-inversion method to make Ni HF with commercial nickel powder as a pristine feedstock(see Supporting Information(SI)for full details),and(2)active Ni O layer fabrication.The as-prepared Ni HFs were calcined in air at200–300°C to obtain x Ni O@Ni HF composites,where x represents the Ni O mass percentage. Figure 1 displays the porous structures and gas permeance behaviors of the Ni HFs.The scanning electron microscopy(SEM)images of the inner and outer surfaces of the Ni HFs(Fig.1a and 1b)show the abundant pores dispersed on these surfaces.The high-magnification SEM images(the insets in Fig.1a and 1b)further indicate an average pore size in the range of1–2μm as well as smooth surfaces.The cross-sectional morphology of a whole Ni HF(Fig.1c)showed characteristic finger-like structures in the outer and inner regions without any visible large microvoids formed.The high-resolution transmission electron microscopy(HRTEM)image of the outer surface of a Ni HF