纳米铁强化生物技术处理染料废水的效能.pdfVIP

中国环境科学 2022,42(12) ：5643~5649 China Environmental Science 纳米铁强化生物技术处理染料废水的效能 * 刘 静,刘爱荣 ,张伟贤 ( 同济大学环境科学与工程学院,污染控制与资源化研究国家重点实验室,上 200092) 摘要：构建纳米铁(nZVI)-生物耦合系统,探讨连续流反应器中耦合系统处理刚果红废水的可行性和可控性.研究发现 nZVI 将刚果红大分子降解为小分 子后,提高了废水的可生化性( 由 0.04 提高至 0.69)并降低了毒性( 由 90.25%降至 30.57%),为生物单元提供良好的环境条件.反应器连续运行期间,耦合系 统对初始浓度为 500mg/L 的刚果红废水脱色率达 99%,COD 从 167mg/L 降低到约 50mg/L.而单一生物系统的脱色率仅为 30%~70%,COD 降至 116mg/L, 且波动较大.研究结果表明,nZVI-生物耦合系统是一种能够深度处理难降解有机染料废水的技术手段. 关键词：纳米铁；纳米铁-生物耦合系统；连续流反应器；刚果红废水 中图分类号：X703.5 文献标识码：A 文章编号：1000-6923(2022)12-5643-07 Research on dyeing wastewater treatment with an integrated nanoscale zero-valent iron and biology technology. LIU Jing, * LIU Ai-rong , ZHANG Wei-xian (College of Environmental Science and Engineering, Tongji University, State Key Laboratory of Pollution Control and Resource Reuse, Shanghai 200092, China). China Environmental Science, 2022,42(12)：5643~5649 Abstract ：A coupling system consisting of nano zero valent iron and membrane bioreactor (nZVI-bio system) was constructed to explore the feasibility and controllability of a continuous flow reactor for the treatment of Congo red (CR) wastewater. Since nZVI pretreatment converts CR macromolecules into small molecules, the biodegradability index denoted by BOD5/COD increased from 0.04 to 0.69 and toxicity reduced from 90.25% to 30.57% compared to the initial CR wastewater, which provides good environmental conditions for biological units. During the continuous operation of the coupling system, CR removal efficiency reached 99% and COD was reduced from 167mg/L to 50mg/L (nZVI pretreatment process at an initial concentration of 500mg/L). However, the color removal efficiency was just 30%~70% and COD was reduced to 116mg/L for a conventional biotreatment system, and the fluctuation