有机化学综合练习题解答.docxVIP

有机化学（下）总复习练习解答 完成反应式 Br 1) NO2 NHCH(CH3)2 (CH3)2CHNH2 NO2 CH CH3 3OH CH3 3 OH CH3  NaNO2 CH HCl O CH3 3OH CH32N + 3 OH CH3 2  N2 CH3 CH3 OH CH3 + 背面迁移 CH3 CH 3CH3 3 H+ OHN OH N O H OH OH OH OHC CH2OH 4HIO4 4HCOOH + HCHO O CH3 O CH3 CCH2CHCH2COOEt  EtONa  CH3 O COOEt COOEt EtONa C O O2 2COOEt O 2 2 OBr O CHO + CH (COOEt) N Br  CH=C(COOEt)2 O 8) + CH2(COOEt)2 EtONa O O OEt  EtONa COOEt 1,NaOH 2,H3O+ OCHO+ O CHO + Cl O 9)  O EtONa COOEt O O OO O O O EtO- O OO O NHCH NH Cl 10) O + CH3CH2C CH  KOH HO C CCH2CH3 11) COOEt COCH3 NaBH COOEt CHCH3 4OH 4 C2H5COOC2H5 + C6H5COOC2H5 EtONa  O C6H5CCHCOOC2H5 CH3 OH N O NHH2SO4 NH CH2OH O OCH3  HIO CH2 OH OCH OH OH OH 4 HCOOH + OHC O 3 OHC 2 2 COOH 1,SOCl2 COCHN2 Ag O CH2COOH 2,CH2N2 H2O EtOOC(CH ) O COOEt EtONa O CH2 CHCOCH3 EtONa CH3O 2 5 O COOEt OHOH CH3 4Ph Ph 4 COOEt H+ CH3O EtONa Ph O C CH3 Ph COOEt CH2CH2COCH3 CH2CHO NaBH CH2CH2OH C6H5COONa + CH2 CHCH2Br C6H5COOCH2CH=CH2 CH3CH2CH2CH N(CH3)3OH - CH3 CH3CH2CH2CH=CH2 + (CH3)3N OHC CHO + HCHO(过量） 浓KOH HOH C CH OH + HCOOK 2 2 (CH ) CHCOCH  F3CCO3H + H2O2 O (CH3)2CHOCCH3 3 2 3 O CH3 Zn Hg HCl COOH CH3 COOH  CHO NaBH4  CH2OH O NH H3 H3O+ OH- O  KOH(s) O N-K+ O CH2NH2 O  PhCH2Br O NCH2Ph O NH O NaOH H2O NH2 Br /NaOH 2OH 2 浓KOH,O 浓KOH, O NH2 OH O  OSCH3 O S CHO COOK + OSCH3 O S CH2OH CH3CH2COCl COCH CH AlCl3 2 3 3O CH3COOCH 3 CH3 Cl N N CH3 + CH3OOCC CCOOCH3 ONOCH3 O N CH3ONa CH3ONa CH3OH,  CH3 COOCH3 N N+ C H N+ N N  N=NC6H5 6 5 H H  H2N NH2 + 2 CH2 OH CH CH2 OH OH H2SO4 As2O3 HOCH2 OHOH OH CHO  3PhNHNH2  HOCH2 OHOH NNHPh NNCH=NNHPh N N OH OH OOBr2 O O 0 C O Br NCH3 N  NH2 + CH2 CHC CH3 ZnCl2 OONO2 O O + CH3 N2Cl N=N CH3 CH3 CH COOH + F ONH2 O 2N O COOH NO2 CH3CHNH O2N O  NO2 O + CH3NH2 300 C O 简单回答下列问题 NHCH3 O 正确命名下列化合物： （Z）-3-氯-3-溴丙烯酸；3-氨基环己胺 判断下列化合物的性质顺序： 酸性由强到弱的顺序： ClCH2COOH CF3CH2OH ClCH2CH2OH CH3CH2OH 碱性由强到弱的顺序： NH2 N N N H H 碱性由强到弱的顺序： CH3CH2CH2NH2  NH2  O CH3CH2CONH2