高磁性聚合物亚微球的制备及其表面接枝聚合的中期报告.docxVIP

高磁性聚合物亚微球的制备及其表面接枝聚合的中期报告 摘要： 本文主要介绍了高磁性聚合物亚微球的制备和表面接枝聚合的中期研究进展。首先介绍了高磁性聚合物亚微球的制备方法，包括自由基乳液聚合、磁性场下乳液聚合、乳液凝胶法等。其次，介绍了表面接枝聚合的方法，包括单体溶液法、共溶剂法、引发剂固定法等。最后，重点介绍了本研究中使用的表面接枝聚合方法，在聚苯乙烯亚微球表面接枝了聚甲基丙烯酸甲酯（MMA）、2-羟乙基甲基丙烯酸（HEMA）和苯乙烯（St）等单体，并对接枝后的亚微球进行了表征，包括磁性测量、透射电子显微镜观察、傅里叶变换红外光谱和热重分析等。结果表明，表面接枝聚合使聚合物亚微球表面具有了新的性能，并为进一步研究高磁性聚合物亚微球的应用奠定了基础。 关键词：高磁性聚合物亚微球；表面接枝聚合；单体溶液法；共溶剂法；引发剂固定法。 Abstract： This paper mainly introduces the mid-term research progress of the preparation of high magnetic polymer submicron spheres and surface grafting polymerization. Firstly, the preparation methods of high magnetic polymer submicron spheres are introduced, including free radical emulsion polymerization, emulsion polymerization under magnetic field, emulsion gel method, etc. Secondly, the methods of surface grafting polymerization are introduced, including monomer solution method, cosolvent method, initiator fixation method, etc. Finally, the surface grafting polymerization method used in this study is mainly introduced. The submicron spheres of polystyrene were grafted with methyl methacrylate (MMA), 2-hydroxyethyl methacrylate (HEMA), and styrene (St), and the grafted submicron spheres were characterized, including magnetic measurement, transmission electron microscopy observation, Fourier transform infrared spectroscopy, and thermal analysis. The results showed that surface graft polymerization gave the polymer submicron spheres new properties, which laid a foundation for further research on the application of high magnetic polymer submicron spheres. Keywords: high magnetic polymer submicron spheres; surface grafting polymerization; monomer solution method; cosolvent method; initiator fixation method.