纳米羟基磷灰石的制备及其对铅离子的吸附研究的中期报告.docxVIP

纳米羟基磷灰石的制备及其对铅离子的吸附研究的中期报告 【摘要】 本文介绍了纳米羟基磷灰石的制备方法以及其对铅离子的吸附研究。制备方法为水热法，在磷酸和氢氧化钙的加入下，在120℃的条件下反应12小时，得到平均晶粒大小在20nm左右的纳米羟基磷灰石。利用扫描电子显微镜（SEM）、透射电子显微镜（TEM）和X射线衍射（XRD）对纳米羟基磷灰石的形貌和晶体结构进行表征，并且采用比表面积测试仪对其比表面积进行测定。吸附实验采用初始铅离子浓度为50mg/L的铅离子溶液，研究吸附剂用量、pH、温度等因素对纳米羟基磷灰石吸附性能的影响，并通过Langmuir与Freundlich等式对吸附过程进行了研究。结果表明，纳米羟基磷灰石对铅离子具有较好的吸附性能，且吸附过程符合Langmuir等温吸附模型。 【关键词】纳米羟基磷灰石；吸附；铅离子；Langmuir等温吸附模型 【Abstract】 This paper introduces the preparation method of nano-hydroxyapatite and its adsorption study on lead ions. The preparation method is hydrothermal method. With the addition of phosphoric acid and calcium hydroxide, the reaction is carried out at 120°C for 12 hours, and nano-hydroxyapatite with an average particle size of about 20nm is obtained. The morphology and crystal structure of nano-hydroxyapatite are characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM) and X-ray diffraction (XRD), and the specific surface area is determined by a surface area analyzer. The adsorption experiment uses a lead ion solution with an initial concentration of 50mg/L, and studies the effect of adsorbent dosage, pH, temperature and other factors on the adsorption performance of nano-hydroxyapatite. The adsorption process is studied through Langmuir and Freundlich equations. The results show that nano-hydroxyapatite has good adsorption performance on lead ions, and the adsorption process conforms to the Langmuir isothermal adsorption model. 【Keywords】Nano-hydroxyapatite; Adsorption; Lead ions; Langmuir isothermal adsorption model