Zielger-Natta复合催化剂的制备及其乙烯聚合的研究的中期报告.docxVIP

Zielger-Natta复合催化剂的制备及其乙烯聚合的研究的中期报告 Abstract: This midterm report summarizes the progress made on the preparation of Ziegler-Natta composite catalysts and their application in ethylene polymerization. The main objective of the study is to develop novel composite catalysts with high activity and selectivity for the production of polyethylene with tailored properties. Introduction: Ziegler-Natta catalysts have been widely used in the industrial production of polyethylene. However, their limitations in terms of activity and selectivity have prompted the development of new types of catalysts. Composite catalysts, which combine different active species in a single catalytic system, have shown promising results in the polymerization of olefins. In this study, we focus on the synthesis and characterization of Ziegler-Natta composite catalysts and their application in the polymerization of ethylene. Experimental Methodology: The catalysts were prepared by impregnating magnesium chloride (MgCl2) with different amounts of TiCl4, followed by activation with different cocatalysts (triethylaluminum, TEA, or methylaluminoxane, MAO). The resulting catalysts were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). Ethylene polymerization was performed in a 1-liter stainless steel reactor under different conditions (temperature, pressure, and polymerization time). The obtained polymers were characterized by gel permeation chromatography (GPC), differential scanning calorimetry (DSC), and nuclear magnetic resonance (NMR). Results and Discussion: The XRD and SEM analyses show that the composite catalysts have a uniform distribution of TiCl4 on the MgCl2 support, indicating a good interaction between the two components. The addition of TEA or MAO as cocatalysts enhances the catalytic activity of the composite catalysts, with MAO showing higher activity than TEA. The ethylene polymerization experiments reveal that the composite catalysts have high activ