乙酸乙酯皂化.docx

T=298.15K T=308.15K Κ0(μS*cm-1) 2070 2050 Κ0(μS*cm-1) 2430 2400 Κ0(μS*cm-1) 2030 Κ0(μS*cm-1) 2370 t/min κt/(μS/cm) (κ0-κt)/t(μS*cm-1*min-1) t/min κt(μS*cm-1) (κ0-κt)/t(μS*cm-1*min-1) 6 1722 54.67 6 1748 108.67 9 1612 48.67 8 1643 94.63 12 1613 43.67 10 1562 83.80 15 1457 39.53 12 1497 75.25 20 1366 34.20 15 1421 65.27 25 1297 30.12 18 1364 57.56 30 1244 26.87 21 1317 51.57 35 1200 24.29 24 1280 46.67 40 1163 22.18 30 1226 39.13 a(mol/l) 0.01009 相对误差 k298.15K(L/mol*min) 5.81 9.64% 文献值k298.16K(L/mol*min) 6.43 k308.17K(L/mol*min) 13.15 10.13% k308.18K(L/mol*min) 11.94 Ea(KJ/mol) 62.394