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- 2024-06-06 发布于北京
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19.13
ReactionsofCarboxylicAcids:
AReviewandaPreview
Acidity(Sections19.4-19.9)ReductionwithLiAlH4(Section15.3)Esterification(Section15.8)ReactionwithThionylChloride(Section12.7)ReactionsalreadydiscussedReactionsofCarboxylicAcids
a-HalogenationDecarboxylationButfirstwerevisitacid-catalyzedesterification
toexamineitsmechanism.NewreactionsinthischapterReactionsofCarboxylicAcids
19.14
MechanismofAcid-CatalyzedEsterification
Acid-catalyzedEsterification+CH3OHCOHOH++H2OCOCH3O Importantfact:theoxygenofthealcoholis
incorporatedintotheesterassho
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