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ExtraProblemsforChapter6–FromCollegeChemistry,page19
1A1.5276-gsampleofCdCl2wasconvertedtometalliccadmiumandcadmium-freeproductsbyelectrolysis.Theweightofthemetalliccadmiumwas0.9367g.IfAr(Cl)=35.453u,whatisAr(Cd)?
Ans.112.4u
2Howmany(a)gramsofH2S,(b)molesofHandofS,(c)gramsofHandofS,(d)moleculesofH2Sarecontainedin0.400molH2S?
Ans.(a)13.63gH2S,(b)0.800molH,0.400molS,(c)0.806gH,13.83gS,(d)2.41×1023molecules
3Aborane(containingonlyBandH)contained88.45%B.Whatisitsempiricalformula?
Ans.B5H7
4Determinethepercentagecompositionofpotassiumcarbonate,K2CO3.
Ans.56.58%K,8.69%C,34.73%O
5Pyrexglasstypicallycontains12.9%B2O3,2.2%Al2O3,3.8%Na2O,0.4%K2O,and80.7%SiO2.Whatistheratioofsilicontoboronatomsintheglass?
Ans.3.6
6AnelementXformsfouroxidescontaining77.4,63.2,69.6,and72.0%X.Ifthecompoundwith77.4%XisXO,whatisX,andwhataretheempiricalformulasoftheothercompounds?
Ans.X=Mn;MnO2,Mn2O3,andMn3O4
7Asampleofimpurecuprite,Cu2O,contains66.6%copper.Assumingthattheimpuritiesdonotcontaincopper,whatpercentageofthesampleisCu2O?
Ans.75.0%Cu2O
8Thedominantpeakinthemassspectrumofanorganiccompoundgaveanuclidicmolecularmassof117.090u.IfitwasknowninadvancethatthecompoundcontainedonlyC,H,andOandthatnomorethanfouroxygenatomsarepresentinthemolecule,whatisitsmolecularformula?
Ans.C6H13O2
9Anorganiccompoundwaspreparedcontainingatleastoneandnomorethantwosulfuratomspermolecule.ThecompoundhadCandH,noN,butOcouldhavebeenpresent.Themolecularmassofthepredominantnuclidicspecieswas110.020u,asdeterminedbymassspectrometry.Whatisthemolecularformulaofthecompound?
Ans.C6H6S
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