Quantum chemistry - PDF Room最新电子版文档.pdf

Quantum chemistry - PDF Room最新电子版文档.pdf

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QUANTUMCHEMISTRY

SECONDEDITION

QUANTUMCHEMISTRY

SECONDEDITION

DonaldA.McQuarrie

DEPARTMENTOFCHEMISTRY

UNIVERSITYOFCALIFORNIA,DAVIS

UNIVERSITYSCIENCEBOOKS

MillValley,California

UniversityScienceBooks

ProductionManager:.JenniferUhlichatWilstedandTaylor

ManuscriptEditor:.JohnMurdzek

Proofreader:.JenniferMcClain

Design:YvonneTsangatWilstedandTaylor

lllustrator:MervinHanson

Compositor:WindfallSoftware,usingZz7j;;X

PrinterBinder:EdwardsBrothersMalloy

Thisbookisprintedonacid-freepaper.

Copyright©2008byUniversityScienceBooks

Reproductionortranslationofanypartofthisworkbeyondthatpem1ittedbySection107or108

ofthe1976UnitedStatesCopyrightActwithoutthepem1issionofthecopyrightowneristmlawful.

RequestsforpermissionorfurtherinformationshouldbeaddressedtothePen11issionsDepartment,

UniversityScienceBooks.

LibraryofCongressCataloging-in-PublicationData

McQua1Tie,DonaldA.(DonaldAllan)

QuantumchemistryIDonaldA.McQua1Tie.-2nded.

p.cm.

Includesindex.

ISBN978-1-891389-50-4(alk.paper)

Quantumchemistry.I.Title.

QD462.M42007

541.28-dc22

2007023879

PrintedintheUnitedStatesofAmerica

109876543

Contents

PrefacetotheSecondEditionxi

CHAPTER1ITheDawnoftheQuantumTheory

1.1BlackbodyRadiation2

1.2PlancksQuantumHypothesis4

1.3ThePhotoelectricEffect8

1.4VibrationsofAtomsinCrystals11

1.5TheHydrogenAtomicSpectrum12

1.6TheRydbergFormula15

1.7AngularMomentum16

1.8

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