(9)--Ch6 Hofmann消除原始文献(1851).pdf

(9)--Ch6 Hofmann消除原始文献(1851).pdf

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[357]

XIV.ResearchesintotheMolecularConstitutionoftheOrganicBases.

A.W.Hofmann,F.C.S.,ProfessoroftheRoyalCollegeofChemistryofLondon.

(SecondMemoir.)CommunicatedhySirJamesClark,Bart.,F.R.S.

ReceivedMarch12,—ReadApril3,1851.

2ABOUTtwelvemonthsagoIhadthehonourofpresentingtotheRoyalSocietyan

2accountofaseriesofresearchesintothemolecularconstitutionofthevolatileorganic

0

2

lbases*:atpresentIbegtosubmittotheconsiderationoftheSocietythehistory

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pofanewgroupofalkaloids,which,althoughintimatelyconnectedwiththeformer

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0bytheirorigin,differfromthemaltogetherbytheirproperties,andespeciallyinnot

1

nbeingvolatile.

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gThemembersofthisnewgroupofalkaloidsaresonumerous,theirdeportmentis

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o

g.sosingular,andtheirderivativesramifyinsomanydirections,thatIhavenotas

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hyetbeenabletocompletethestudyofthesesubstancesinalltheirbearings;noris

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litmyintentiontogofullyintothechemistryofthesubjectinthepresentcom­

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pmunication,myobjectbeingmerelytoestablishtheexistenceofthesebodies,and

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itogiveageneraloutlineoftheirconnectionwiththevolatilebases,andoftheirmost

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sprominentchemicalandphysicalproperties,reservingadetaileddescriptionoftheir

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ysaltsandderivativestoafuturememoir.

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/Inthepaperabovereferredto,Iadvancedthepositionthatthemajor

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