添加亚微米Fe2O3对Fe-Ni-Cu-C粉末冶金材料组织与性能的影响.docx

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第20卷第4期粉末冶金材料科学与工程

Vol.20No.4MaterialsScienceandEngineeringofPowderMetallurgy

2015年8月Aug.2015

添加亚微米Fe?O?对Fe-Ni-Cu-C粉末冶金材料组织与性能的影响

滕浩，李佑福，李志友，周科朝

(中南大学粉末冶金国家重点实验室，长沙410083)

摘要；采用亚微米级Fe?O?粉末作为烧结助剂制备Fe-Ni-Cu-C预混合粉，考察Fe?O?颗粒在混合料中的分布状态、Fe?O?添加量对材料的成形与烧结密度以及显微组织和力学性能的影响。结果表明，亚微米Fe?O?粉末可均匀分布在预混料中，但当Fe?O?粉末添加的质量分数超过0.3%时材料的压制与烧结密度明显下降；添加少量的亚微米Fe?O?粉末可提高合金的力学性能，Fe?O?粉末的添加量为0.3%时，合金的强度、韧性和伸长率较未添加Fe?O?粉末时分别提高7.3%、5.8%和4.8%;由于亚微米Fe?O?还原成微细铁粉后具有高活性，坯体烧结时铁基颗粒间的烧结连接率增大，拉伸断口形貌呈较多的韧窝组织，且烧结体中的孔隙圆化。

关键词：铁基粉末冶金；Fe-Ni-Cu-C;Fe?O?;烧结；力学性能

中图分类号：TF124文献标识码：A文章编号：1673-0224(2015)4-584-06

Effectofsub-micronFe?O?additiononmicrostructureand

mechanicalpropertiesofFe-Ni-Cu-Cpowdermetallurgymaterials

TENGHao,LIYou-fu,LIZhi-you,ZHOUKe-chao

(StateKeyLaboratoryofPowderMetallurgy,CentralSouthUniversity,Changsha410083,China)

Abstract:Fe-Ni-Cu-Cpremixpowderswerepreparedwithsub-micronFe?O?powdersasasinteringaid.DistributionstatusofFe?O?particlesinthepremix,effectofFe?O?contentonthegreenandsintereddensity,andthemicrostructureandmechanicalpropertiesofthesinteredmaterialswereinvestigated.Theresultsshowthatthesub-micronFe?O?particlesdistributeuniformlyinthepremix,whilethegreenandsintereddensitydecreaseobviouslywhentheFe?O?contentisabove0.3%.ComparedwiththatofsamplewithnoFe?O?powderadding,themechanicalpropertiesofthealloyareimprovedbyadding0.3%sub-micronFe?O?powder,thetensilestrength,impacttoughnessandelongationofthealloyincreaseby7.3%,5.8%and4.8%,respectively.Forthehighsinteractivityofultrafineironparticlesreducedfromthesub-micronFe?O?powder,theconnectionratebetweentheiron-basedparticlesincreasesinthesinteringprocess,themicrostructurewithmoredimp